(d) On problem set 1 we considered the alkene complex [Mn(CO)s(Ph2C=CPH2)] . This complex and two related complexes are depicted below. Order these complexes from having the MOST metallocyclopropane character to having the LEAST metallocyclopropoane character. Explain your ranking. *Note: Complexes are drawn as an olefin complex for clarity. This does not imply anything in regards to the electronic structure of the coordinated alkene* 7- Ph Ph CS 7- Ph Ph со OCMn Ph Ph ÇNME MENC.. SCMn SC Mn- MENC čs Ph Ph CO Ph Ph ČNME E Ph Ph

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(d) On problem set 1 we considered the alkene complex [Mn(CO)s(PhzC=CPH2)]. This complex and two related
complexes are depicted below. Order these complexes from having the MOST metallocyclopropane character to
having the LEAST metallocyclopropoane character. Explain your ranking.
*Note: Complexes are drawn as an olefin complex for clarity. This does not imply anything in regards to the
electronic structure of the coordinated alkene*
7-
Ph Ph
CS
Ph Ph
CNME E
Ph Ph
CO
SCMn
sc
cs
Ph Ph
MeNCM
MENC
čo
Ph Ph
ČNMe
Ph Ph
Transcribed Image Text:(d) On problem set 1 we considered the alkene complex [Mn(CO)s(PhzC=CPH2)]. This complex and two related complexes are depicted below. Order these complexes from having the MOST metallocyclopropane character to having the LEAST metallocyclopropoane character. Explain your ranking. *Note: Complexes are drawn as an olefin complex for clarity. This does not imply anything in regards to the electronic structure of the coordinated alkene* 7- Ph Ph CS Ph Ph CNME E Ph Ph CO SCMn sc cs Ph Ph MeNCM MENC čo Ph Ph ČNMe Ph Ph
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