Electronic Effects
The effect of electrons that are located in the chemical bonds within the atoms of the molecule is termed an electronic effect. The electronic effect is also explained as the effect through which the reactivity of the compound in one portion is controlled by the electron repulsion or attraction producing in another portion of the molecule.
Drawing Resonance Forms
In organic chemistry, resonance may be a mental exercise that illustrates the delocalization of electrons inside molecules within the valence bond theory of octet bonding. It entails creating several Lewis structures that, when combined, reflect the molecule's entire electronic structure. One Lewis diagram cannot explain the bonding (lone pair, double bond, octet) elaborately. A hybrid describes a combination of possible resonance structures that represents the entire delocalization of electrons within the molecule.
Using Molecular Structure To Predict Equilibrium
Equilibrium does not always imply an equal presence of reactants and products. This signifies that the reaction reaches a point when reactant and product quantities remain constant as the rate of forward and backward reaction is the same. Molecular structures of various compounds can help in predicting equilibrium.
![**Chemistry 241 Quiz 11**
**November 17, 2019, 70 points**
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**Last Name: _____________________ First Name: _____________________**
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Note these acronyms:
- HOAc = Acetic Acid
- NaOAc = Sodium Acetate
- THF = tetrahydrofuran
- Ph = Phenyl = C6H5
- DMSO = Dimethyl Sulfoxide
- H3C-O-H = methanol
- NBS = N-Bromo succinimide
- LDA = Lithium Diisopropylamide
**Chemical Structures:**
- Acetone = ![Acetone Structure](https://i.imgur.com/YrMwvEK.png)
- Acetic Acid = ![Acetic Acid Structure](https://i.imgur.com/K5R0xMY.png)
- THF = ![THF Structure](https://i.imgur.com/NhNh8Nk.png)
- DMSO = ![DMSO Structure](https://i.imgur.com/Xf1SiCC.png)
- Ph = ![Phenyl Structure](https://i.imgur.com/wVYMKd8.png)
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1. **Write the organic and inorganic products of the following reactions. Indicate cis or trans, axial or equatorial, or R or S or racemic, where appropriate. If there is no reaction write NR.**
**d)**
\[ \text{Structure: } \]
\[ \quad \overset{\text{THF solvent}}{\longrightarrow} \]
**e)**
\[ \text{Structure: } \]
\[ + \text{NaOCH}_3 \text{, HOCH}_2\text{CH}_3 \text{ solvent} \overset{\longrightarrow} \]
**f)**
\[ \text{Structure: } \]
\[ \quad \overset{\longrightarrow} \]
[Diagrams of reaction structures are present.]
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### Explanation of Diagrams:
- **Reaction (d)**: Involves a chorinated benzene derivative reacting in a tetrahydrofuran (THF) solvent. The structure shows a triple bond extending from the benzene ring, indicative of an alkyne.
- **Reaction (e)**: Features a chiral silicon-containing compound reacting with a sodium methoxide/ethanol solvent system. The structure demonstrates the](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F0b2d8d84-896e-4f9e-963b-da7844b9b0f5%2F28d0315c-b22e-4d6e-a777-c53457993415%2Fa2echvw_processed.jpeg&w=3840&q=75)
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