d) Fill in the MO for peroxide: e) According to the MO diagram is peroxide diamagnetic or paramagnetic? (circle correct choice) f) What is the bond order of peroxide? g) How does this differ from O₂2 (notes page 104)? 02s Does this make sense?
Formal Charges
Formal charges have an important role in organic chemistry since this concept helps us to know whether an atom in a molecule is neutral/bears a positive or negative charge. Even if some molecules are neutral, the atoms within that molecule need not be neutral atoms.
Polarity Of Water
In simple chemical terms, polarity refers to the separation of charges in a chemical species leading into formation of two polar ends which are positively charged end and negatively charged end. Polarity in any molecule occurs due to the differences in the electronegativities of the bonded atoms. Water, as we all know has two hydrogen atoms bonded to an oxygen atom. As oxygen is more electronegative than hydrogen thus, there exists polarity in the bonds which is why water is known as a polar solvent.
Valence Bond Theory Vbt
Valence bond theory (VBT) in simple terms explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. It gives a quantum mechanical approach to the formation of covalent bonds with the help of wavefunctions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.
![2. Consider peroxide, \( \text{O}_2^{2-} \):
a) How many total valence electrons are in \( \text{O}_2^{2-} \)?
\[
\text{Answer: } 14
\]
b) Draw the Lewis structure for peroxide:
\[
[:\text{O}::\text{O}:]^{2-}
\]
c) According to the Lewis structure is peroxide diamagnetic or paramagnetic? (circle correct choice)
\[ \text{Diamagnetic} \]
d) Fill in the MO (Molecular Orbital) for peroxide:
- The diagram lists orbitals in the following order with occupancy indicated by shading:
- \( \sigma_{2s} \): Filled
- \( \sigma_{2s}^* \): Empty
- \( \sigma_{2p_x} \): Filled
- \( \pi_{2p_y}, \pi_{2p_z} \): Filled
- \( \pi_{2p_y}^*, \pi_{2p_z}^* \): Empty
- \( \sigma_{2p_z}^* \): Empty
e) According to the MO diagram is peroxide diamagnetic or paramagnetic? (circle correct choice)
\[ \text{Diamagnetic} \]
f) What is the bond order of peroxide?
\[ \_\_\_\_ \]
Does this make sense?
\[ \_\_\_\_ \]
g) How does this differ from \( \text{O}_2 \) (notes page 104)?
\[ \_\_\_\_ \]
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