Crud Chemicals is producing a casting resin that can be made using either (i) AA and BB monomers or (ii) an AB-type monomer {A & B represent different functional groups, like alcohol and carboxylic acids). A catalyst is added to promote polymerization in the mold. The material has many useful properties, but is deficient in heat and solvent resistance. A proposal is made to improve heat and solvent resistance by adding a tetrafunctional monomer (A4) to the mix to provide crosslinks. Unfortunately, no one in-house knows if this will work, or if the added A4 will form a gel, so they call you in as a consultant. Evaluate their idea to use A4 as a crosslinking agent for both types of polymerizations (i and ii).
Crud Chemicals is producing a casting resin that can be made using either (i) AA and BB monomers or (ii) an AB-type monomer {A & B represent different functional groups, like alcohol and carboxylic acids). A catalyst is added to promote polymerization in the mold. The material has many useful properties, but is deficient in heat and solvent resistance. A proposal is made to improve heat and solvent resistance by adding a tetrafunctional monomer (A4) to the mix to provide crosslinks. Unfortunately, no one in-house knows if this will work, or if the added A4 will form a gel, so they call you in as a consultant. Evaluate their idea to use A4 as a crosslinking agent for both types of polymerizations (i and ii).
Chemistry & Chemical Reactivity
10th Edition
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter23: Carbon: Not Just Another Element
Section: Chapter Questions
Problem 120SCQ
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Crud Chemicals is producing a casting resin that can be made using either (i) AA and BB monomers or (ii) an AB-type monomer {A & B represent different functional groups , like alcohol and carboxylic acids ). A catalyst is added to promote polymerization in the mold. The material has many useful properties, but is deficient in heat and solvent resistance. A proposal is made to improve heat and solvent resistance by adding a tetrafunctional monomer (A4) to the mix to provide crosslinks. Unfortunately, no one in-house knows if this will work, or if the added A4 will form a gel, so they call you in as a consultant. Evaluate their idea to use A4 as a crosslinking agent for both types of polymerizations (i and ii).
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