Cr3+ (1 M) Cr2+ (1 M) T13+ (1 M) T13+ (aq) + 3e-> TI (s) Cr2 (aq) Cr3 (aq) + e- Using the list of standard reduction potentials below, calculate the standard reduction potential (E°red) for the thallium hal reaction given that the cell potential (Ecen) under standard conditions is +1.14 V. Hint: You will not find a standard reduction potential for thallium in the table; that's what you're calculating!

Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter18: Electrochemistry
Section: Chapter Questions
Problem 18.71QE
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Cr3+ (1 M)
Cr2+ (1 M)
T13+ (1 M)
T13+ (aq) + 3e-→ TI (s)
Cr2+ (aq) Cr3+ (aq) + e-
Using the list of standard reduction potentials below, calculate the standard reduction potential (E°red) for the thallium hal
reaction given that the cell potential (E°cel) under standard conditions is +1.14 V.
Hint: You will not fınd a standard reduction potential for thallium in the table; that's what you're calculating!
Half-Reaction
E°red (volts)
Li* (aq) + e → Li (s)
- 3.04
Fe? (aq) + 2e → Fe (s)
Cr (aq) +
-0.45
e → Cr* (aq)
-0.41
Co2* (aq) + 2e → Co (s)
-0.28
2H (aq) + 2e → H2 (g)
0.00
(reference electrode)
Cu+ (aq) + 2 e → Cu (s)
+0.52
L (s) + 2e → 21 (aq)
+0.54
Ag (aq) + e → Ag (s)
Hg (aq) + 2e Hg (e)
+0.80
+0.85
F2 (g) + 2e → 2F (aq)
+2.87
DELL
Esc
F1
F2
F3
F4
F5
F6
F7
F8
F9
F10
%23
2$
&
3
4
6
7
T.
Y
Transcribed Image Text:Cr3+ (1 M) Cr2+ (1 M) T13+ (1 M) T13+ (aq) + 3e-→ TI (s) Cr2+ (aq) Cr3+ (aq) + e- Using the list of standard reduction potentials below, calculate the standard reduction potential (E°red) for the thallium hal reaction given that the cell potential (E°cel) under standard conditions is +1.14 V. Hint: You will not fınd a standard reduction potential for thallium in the table; that's what you're calculating! Half-Reaction E°red (volts) Li* (aq) + e → Li (s) - 3.04 Fe? (aq) + 2e → Fe (s) Cr (aq) + -0.45 e → Cr* (aq) -0.41 Co2* (aq) + 2e → Co (s) -0.28 2H (aq) + 2e → H2 (g) 0.00 (reference electrode) Cu+ (aq) + 2 e → Cu (s) +0.52 L (s) + 2e → 21 (aq) +0.54 Ag (aq) + e → Ag (s) Hg (aq) + 2e Hg (e) +0.80 +0.85 F2 (g) + 2e → 2F (aq) +2.87 DELL Esc F1 F2 F3 F4 F5 F6 F7 F8 F9 F10 %23 2$ & 3 4 6 7 T. Y
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