Could you draw the full arrow pushing mechanism for each of these and give the proper name for this reaction (What is happening at each step? What atom is nucleophilic? Which atom is electrophilic? Which bonds are made? Which bonds are broken?) CO₂H CO₂H CO₂H HO HO NH2 NH2 NH2 HO 1. ACCI (1.3 equiv), CF3CO2H (rt, 10 min) 2. Some EtOH, then evaporation and recryst. from EtOH-Et₂O CO₂H CO₂H CO₂H NH2 HCI NH2 HCI NH2 HCI 90% 80% 70% 요이요이 Other acyl chlorides tested in O-acylation of serine, threonine and tyrosine CI
Could you draw the full arrow pushing mechanism for each of these and give the proper name for this reaction (What is happening at each step? What atom is nucleophilic? Which atom is electrophilic? Which bonds are made? Which bonds are broken?) CO₂H CO₂H CO₂H HO HO NH2 NH2 NH2 HO 1. ACCI (1.3 equiv), CF3CO2H (rt, 10 min) 2. Some EtOH, then evaporation and recryst. from EtOH-Et₂O CO₂H CO₂H CO₂H NH2 HCI NH2 HCI NH2 HCI 90% 80% 70% 요이요이 Other acyl chlorides tested in O-acylation of serine, threonine and tyrosine CI
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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