Construct a titration curve by plotting pH vs. VNªOH added.

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Exercise Construct a titration curve by plotting pH vs. VNaOH added.
HCl(aq) + NaOH(aq)
H₂O(1) + NaCl(aq)
Volume NaOH (mL) [H'] pH
0.00
5.00
10.00
15.00
20.00
25.00
30.00
35.00
40.00
45.00
48.00
50.00
52.00
55.00
60.00
65.00
70.00
75.00
80.00
85.00
90
95
100
1×107
Hints:
The pH of the solution is calculated using the following equations:
[H]=
(a) Initial conditions (VNaOH = 0), [H] = [HCI]
(b) After initial addition of NaOH and before the end point:
[H]=
MHCI VHCI-M
VHCI + V NaOH
1x10-14
XV.
titrant: NaOH, 0.1M
(c) At the end point (VNaOH = 50 mL), all the HCI is being consumed and the acidity
of the solution comes from auto ionization of water which is:
[H"]=1x107
(d) After the end point:
Mo
analyte: HC1, 0.1 M, 50 ml.
NaOH *V NaOH
NaOff
V +V₂C²
NaOH
Transcribed Image Text:Exercise Construct a titration curve by plotting pH vs. VNaOH added. HCl(aq) + NaOH(aq) H₂O(1) + NaCl(aq) Volume NaOH (mL) [H'] pH 0.00 5.00 10.00 15.00 20.00 25.00 30.00 35.00 40.00 45.00 48.00 50.00 52.00 55.00 60.00 65.00 70.00 75.00 80.00 85.00 90 95 100 1×107 Hints: The pH of the solution is calculated using the following equations: [H]= (a) Initial conditions (VNaOH = 0), [H] = [HCI] (b) After initial addition of NaOH and before the end point: [H]= MHCI VHCI-M VHCI + V NaOH 1x10-14 XV. titrant: NaOH, 0.1M (c) At the end point (VNaOH = 50 mL), all the HCI is being consumed and the acidity of the solution comes from auto ionization of water which is: [H"]=1x107 (d) After the end point: Mo analyte: HC1, 0.1 M, 50 ml. NaOH *V NaOH NaOff V +V₂C² NaOH
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