Construct a graph and conversion at equilibrium in a reactor where the occurrence, (A⇋S) of direct and inverse first order, as a function of temperature T, is known: H (298 K)=-40,000 cal/mol; H. (298 K)=-60,000 cal/mol; CM 50 cal/mol.K; CPS 50 cal/mol.K and equilibrium constant K. 100,000 to 298 K.-Is this occurrence endo or exothermic? Why?-Demonstrate that the operating line of the adiabatic tubular reactor (x versus T) is a straight line, if the thermodynamic properties are assumed constant.-Calculate the maximum conversion that could be obtained if the tubular reactor was fed at 300 K and operated adiabatically.-Based on the deduced solution, indicate how it would be possible to change the orientation of this line of operation
Construct a graph and conversion at equilibrium in a reactor where the occurrence, (A⇋S) of direct and inverse first order, as a function of temperature T, is known: H (298 K)=-40,000 cal/mol; H. (298 K)=-60,000 cal/mol; CM 50 cal/mol.K; CPS 50 cal/mol.K and equilibrium constant K. 100,000 to 298 K.-Is this occurrence endo or exothermic? Why?-Demonstrate that the operating line of the adiabatic tubular reactor (x versus T) is a straight line, if the thermodynamic properties are assumed constant.-Calculate the maximum conversion that could be obtained if the tubular reactor was fed at 300 K and operated adiabatically.-Based on the deduced solution, indicate how it would be possible to change the orientation of this line of operation
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Construct a graph and conversion at equilibrium in a reactor where the occurrence, (A⇋S) of direct and inverse first order, as a function of temperature T, is known: H (298 K)=-40,000 cal/mol; H. (298 K)=-60,000 cal/mol; CM 50 cal/mol.K; CPS 50 cal/mol.K and equilibrium constant K. 100,000 to 298 K.
-Is this occurrence endo or exothermic? Why?
-Demonstrate that the operating line of the adiabatic tubular reactor (x versus T) is a straight line, if the
-Calculate the maximum conversion that could be obtained if the tubular reactor was fed at 300 K and operated adiabatically.
-Based on the deduced solution, indicate how it would be possible to change the orientation of this line of operation
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