Consider 3,3-dimethylpentane.   Using a Newman projection formula, draw the most stable conformation, sighting along the C2-C3 bond.  Compute the total strain energy for this conformation.  Refer to strain energy values given below .............................................................................. Strain energies with respect to atoms/groups bonded to C-C (one atom/group bonded to each C) H <---> H  eclipsed :  4 kJ/mol CH3 <---> H  eclipsed:  6 kJ/mol CH3 <----> CH3 eclipsed:  11 kJ/mol CH3 <----> CH3 gauche staggered:   3.8 kJ/mol

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Consider 3,3-dimethylpentane.   Using a Newman projection formula, draw the most stable conformation, sighting along the C2-C3 bond.  Compute the total strain energy for this conformation.  Refer to strain energy values given below

..............................................................................

Strain energies with respect to atoms/groups bonded to C-C (one atom/group bonded to each C)

H <---> H  eclipsed :  4 kJ/mol

CH3 <---> H  eclipsed:  6 kJ/mol

CH3 <----> CH3 eclipsed:  11 kJ/mol

CH3 <----> CH3 gauche staggered:   3.8 kJ/mol

 

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