Consider the tests that aided you to confirm your unknown. Write chemical equations for those reactions between your unknown using YOUR structure and the readgents used that gave you a positive test.  I confirmed my unknown as 2-methyl-2-propanol I'm getting a headach just looking at this problem so I am going to attach the two tests from my lab notebook that came up as positive (alcohol) Thank you so much

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Consider the tests that aided you to confirm your unknown. Write chemical equations for those reactions between your unknown using YOUR structure and the readgents used that gave you a positive test. 

I confirmed my unknown as 2-methyl-2-propanol

I'm getting a headach just looking at this problem so I am going to attach the two tests from my lab notebook that came up as positive (alcohol)

Thank you so much

**Test #8: Lucas Test for Alcohol Type**

**Procedure:**  
Time is a crucial factor in this test, so prepare to start your watch. Add 9 drops of the unknown substance to 25 drops of the Lucas reagent. **CAUTION:** The reagent is corrosive and toxic. Mix the contents and let the test tube stand while noting the time. The formation of a cloudy suspension (gelatinous) indicates the production of an alkyl halide, which is a positive test result. The key aspect to observe is the time taken for the suspension to form.

**Discussion:**  
- **Tertiary alcohols** react rapidly, within 1 minute.
- **Secondary (2°) alcohols** take up to 5-6 minutes.
- **Primary (1°) alcohols** do not react within this timeframe.

The zinc chloride in the reagent acts as a catalyst for the reaction.

**Chemical Reaction:**

\[ \text{R}_3\text{C-OH} + \text{HCl} \xrightarrow{\text{ZnCl}_2} \text{R}_3\text{C-Cl} + \text{H}_2\text{O} \]

- The appearance of cloudiness indicates the formation of the alkyl chloride (R₃C-Cl).
Transcribed Image Text:**Test #8: Lucas Test for Alcohol Type** **Procedure:** Time is a crucial factor in this test, so prepare to start your watch. Add 9 drops of the unknown substance to 25 drops of the Lucas reagent. **CAUTION:** The reagent is corrosive and toxic. Mix the contents and let the test tube stand while noting the time. The formation of a cloudy suspension (gelatinous) indicates the production of an alkyl halide, which is a positive test result. The key aspect to observe is the time taken for the suspension to form. **Discussion:** - **Tertiary alcohols** react rapidly, within 1 minute. - **Secondary (2°) alcohols** take up to 5-6 minutes. - **Primary (1°) alcohols** do not react within this timeframe. The zinc chloride in the reagent acts as a catalyst for the reaction. **Chemical Reaction:** \[ \text{R}_3\text{C-OH} + \text{HCl} \xrightarrow{\text{ZnCl}_2} \text{R}_3\text{C-Cl} + \text{H}_2\text{O} \] - The appearance of cloudiness indicates the formation of the alkyl chloride (R₃C-Cl).
**Test # 7: Ceric Nitrate Test for Alcohols**

If tests 3, 4, and 6 were negative, this test is used to reveal an alcohol. Three drops of the unknown are added to 7-8 drops of the reagent, ceric nitrate, in a 4-inch test tube, with shaking. The rapid appearance of a red color, due to complexation of the cerium (IV) ion with the alcohol, is a positive test.

**Discussion:** This test works for most alcohols up to 10-carbon alcohols. If your test result is positive for alcohols, proceed to Test # 8 (Lucas Test) to determine the type of alcohol.

**Chemical Reaction:**

\[ \text{R-OH} + \left( \text{NH}_4 \right)_2 \left[ \text{Ce} \left( \text{NO}_3 \right)_6 \right] \longrightarrow 2 \text{NH}_4^+ + \left[ \left( \text{RO} \right) \text{Ce} \left( \text{NO}_3 \right)_5 \right]^{2-} + \text{NO}_3^- + \text{H}^+ \]

- **Yellow:** The color of the ceric ammonium nitrate starting complex.
- **Red Complex:** The color indicates a positive reaction with alcohol.

This test is useful in identifying the presence of alcohols in a substance by observing a color change upon reaction.
Transcribed Image Text:**Test # 7: Ceric Nitrate Test for Alcohols** If tests 3, 4, and 6 were negative, this test is used to reveal an alcohol. Three drops of the unknown are added to 7-8 drops of the reagent, ceric nitrate, in a 4-inch test tube, with shaking. The rapid appearance of a red color, due to complexation of the cerium (IV) ion with the alcohol, is a positive test. **Discussion:** This test works for most alcohols up to 10-carbon alcohols. If your test result is positive for alcohols, proceed to Test # 8 (Lucas Test) to determine the type of alcohol. **Chemical Reaction:** \[ \text{R-OH} + \left( \text{NH}_4 \right)_2 \left[ \text{Ce} \left( \text{NO}_3 \right)_6 \right] \longrightarrow 2 \text{NH}_4^+ + \left[ \left( \text{RO} \right) \text{Ce} \left( \text{NO}_3 \right)_5 \right]^{2-} + \text{NO}_3^- + \text{H}^+ \] - **Yellow:** The color of the ceric ammonium nitrate starting complex. - **Red Complex:** The color indicates a positive reaction with alcohol. This test is useful in identifying the presence of alcohols in a substance by observing a color change upon reaction.
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