Consider the synthesis of ammonia: 3H2(g) + N,(g) = 2NH3(g), which has AH° = -92.4 kJ/mol and AS° = -199 J/mol at 298 K. For this problem, you may assume all gases behave ideally. a. Calculate Kp for this reaction. b. If a mixture of 1.00 mol H2 and 1.00 mol of N2 is combined in a 10.0 L container and allowed to reach equilibrium, use Kp to calculate the final pressures of H2 and N2. c. Calculate Kc for this reaction. d. If a mixture of 1.00 mol H2 and 1.00 mol of N2 is combined in a 10.0 L container and allowed to reach equilibrium, use Kc to calculate the final concentration of H2 and N2. e. Convert your answers from part (b) and part (d) into the same units -- how do they compare?

Chemistry: Principles and Reactions
8th Edition
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Author:William L. Masterton, Cecile N. Hurley
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Chapter12: Gaseous Chemical Equilibrium
Section: Chapter Questions
Problem 54QAP: Consider the following hypothetical reaction: X2(g)+R(s)X2R(g) R has a molar mass of 73 g/mol. When...
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Consider the synthesis of ammonia: 3H2(g) + N2(g) = 2NH3(g), which has AHº
-92.4 kJ/mol and AS° = -199 J/mol at 298 K. For this problem, you may assume
all gases behave ideally.
a. Calculate Kp for this reaction.
b. If a mixture of 1.00 mol H2 and 1.00 mol of N2 is combined in a 10.0 L container
and allowed to reach equilibrium, use Kp to calculate the final pressures of H2 and
N2.
c. Calculate Kç for this reaction.
d. If a mixture of 1.00 mol H2 and 1.00 mol of N2 is combined in a 10.0 L container
and allowed to reach equilibrium, use Kc to calculate the final concentration of H2
and N2.
e. Convert your answers from part (b) and part (d) into the same units -- how do they
compare?
Transcribed Image Text:Consider the synthesis of ammonia: 3H2(g) + N2(g) = 2NH3(g), which has AHº -92.4 kJ/mol and AS° = -199 J/mol at 298 K. For this problem, you may assume all gases behave ideally. a. Calculate Kp for this reaction. b. If a mixture of 1.00 mol H2 and 1.00 mol of N2 is combined in a 10.0 L container and allowed to reach equilibrium, use Kp to calculate the final pressures of H2 and N2. c. Calculate Kç for this reaction. d. If a mixture of 1.00 mol H2 and 1.00 mol of N2 is combined in a 10.0 L container and allowed to reach equilibrium, use Kc to calculate the final concentration of H2 and N2. e. Convert your answers from part (b) and part (d) into the same units -- how do they compare?
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