Consider the reaction of 2-bromo-2-methylpropane with water, shown below, to answer the following question(s) CH3 CH3 H₂O H3C-C-OH + HBr H3CC-Br
Consider the reaction of 2-bromo-2-methylpropane with water, shown below, to answer the following question(s) CH3 CH3 H₂O H3C-C-OH + HBr H3CC-Br
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![**Title: Reaction Mechanism of 2-Bromo-2-methylpropane with Water**
**Introduction:**
This page explores the reaction of 2-bromo-2-methylpropane with water and provides a detailed analysis of the step-by-step mechanism.
**Reaction Overview:**
Consider the reaction of 2-bromo-2-methylpropane with water, as represented below:
\[ \text{CH}_3 \text{CH}_3\text{C} - \text{CH}_3\text{Br} + \text{H}_2\text{O} \rightarrow \text{CH}_3\text{CH}_3\text{C} - \text{CH}_3\text{OH} + \text{HBr} \]
**Diagram 1: First Step of the Reaction**
The first step of this reaction is shown below:
\[ \text{CH}_3\text{CH}_3\text{C} - \text{CH}_3\text{Br} \leftrightarrow \text{CH}_3\text{CH}_3\text{C}^+ - \text{CH}_3 + \text{Br}^- \]
Where \( A \) represents the 2-bromo-2-methylpropane, and \( B \) represents the carbocation intermediate formed after the departure of the bromide ion.
**Diagram 2: Second and Third Steps of the Reaction**
The second and third steps of the reaction are shown below:
\[ \text{CH}_3\text{CH}_3\text{C}^+ - \text{CH}_3 + \text{H}_2\text{O} \leftrightarrow \text{CH}_3\text{CH}_3\text{C}\text{OH}_2^+ - \text{CH}_3 \rightarrow \text{CH}_3\text{CH}_3\text{C} - \text{CH}_3\text{OH} + \text{H}_3\text{O}^+ \]
**Mechanism Explanation with Electron Flow:**
- In **Diagram 1**, 2-bromo-2-methylpropane (**A**) undergoes heterolysis to form a tertiary carbocation (**](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F5dad743c-ee0b-4240-a1ae-7d99106136e7%2F028b8328-3345-40b7-93f6-32f767e9e043%2Fyxficdj_processed.jpeg&w=3840&q=75)
Transcribed Image Text:**Title: Reaction Mechanism of 2-Bromo-2-methylpropane with Water**
**Introduction:**
This page explores the reaction of 2-bromo-2-methylpropane with water and provides a detailed analysis of the step-by-step mechanism.
**Reaction Overview:**
Consider the reaction of 2-bromo-2-methylpropane with water, as represented below:
\[ \text{CH}_3 \text{CH}_3\text{C} - \text{CH}_3\text{Br} + \text{H}_2\text{O} \rightarrow \text{CH}_3\text{CH}_3\text{C} - \text{CH}_3\text{OH} + \text{HBr} \]
**Diagram 1: First Step of the Reaction**
The first step of this reaction is shown below:
\[ \text{CH}_3\text{CH}_3\text{C} - \text{CH}_3\text{Br} \leftrightarrow \text{CH}_3\text{CH}_3\text{C}^+ - \text{CH}_3 + \text{Br}^- \]
Where \( A \) represents the 2-bromo-2-methylpropane, and \( B \) represents the carbocation intermediate formed after the departure of the bromide ion.
**Diagram 2: Second and Third Steps of the Reaction**
The second and third steps of the reaction are shown below:
\[ \text{CH}_3\text{CH}_3\text{C}^+ - \text{CH}_3 + \text{H}_2\text{O} \leftrightarrow \text{CH}_3\text{CH}_3\text{C}\text{OH}_2^+ - \text{CH}_3 \rightarrow \text{CH}_3\text{CH}_3\text{C} - \text{CH}_3\text{OH} + \text{H}_3\text{O}^+ \]
**Mechanism Explanation with Electron Flow:**
- In **Diagram 1**, 2-bromo-2-methylpropane (**A**) undergoes heterolysis to form a tertiary carbocation (**
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