Consider the reaction C12H22O11(s) + 1202 (g)→12CO2(g) +11H2O(1) in which 10.0 g of sucrose, C12H22011, was burned in a bomb calorimeter with a heat capacity of 7.50 kJ/°C. The temperature increase inside the calorimeter was found to be 22.0 °C. Calculate the change in internal energy, AE, for this reaction per mole of sucrose. Express the change in internal energy in kilojoules per mole to three significant figures.

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
icon
Concept explainers
Question
100%
Consider the reaction
C12 H22O11 (s) + 1202(g)→12CO2(g) + 11H20(1)
in which 10.0 g of sucrose, C12H22011, was burned in a bomb calorimeter with a heat capacity of 7.50 kJ/°C. The temperature increase inside
the calorimeter was found to be 22.0 °C. Calculate the change in internal energy, AE, for this reaction per mole of sucrose.
Express the change in internal energy in kilojoules per mole to three significant figures.
Transcribed Image Text:Consider the reaction C12 H22O11 (s) + 1202(g)→12CO2(g) + 11H20(1) in which 10.0 g of sucrose, C12H22011, was burned in a bomb calorimeter with a heat capacity of 7.50 kJ/°C. The temperature increase inside the calorimeter was found to be 22.0 °C. Calculate the change in internal energy, AE, for this reaction per mole of sucrose. Express the change in internal energy in kilojoules per mole to three significant figures.
A calorimeter is an insulated device in which a chemical
reaction is contained. By measuring the temperature change,
AT, we can calculate the heat released or absorbed during
the reaction using the following equation:
q= specific heat x mass x AT
Or, if the calorimeter has a predetermined heat capacity, C,
the equation becomes
q=C x AT
At constant pressure, the enthalpy change for the reaction,
AH, is equal to the heat, qp; that is,
AH= 4p
but it is usually expressed per mole of reactant and with a
sign opposite to that of q for the surroundings. The total
internal energy change, AE (sometimes referred to as
AU), is the sum of heat, q, and work done, w:
AE=q+w
However, at constant volume (as with a bomb calorimeter)
w =0 and so AE= qv-
Transcribed Image Text:A calorimeter is an insulated device in which a chemical reaction is contained. By measuring the temperature change, AT, we can calculate the heat released or absorbed during the reaction using the following equation: q= specific heat x mass x AT Or, if the calorimeter has a predetermined heat capacity, C, the equation becomes q=C x AT At constant pressure, the enthalpy change for the reaction, AH, is equal to the heat, qp; that is, AH= 4p but it is usually expressed per mole of reactant and with a sign opposite to that of q for the surroundings. The total internal energy change, AE (sometimes referred to as AU), is the sum of heat, q, and work done, w: AE=q+w However, at constant volume (as with a bomb calorimeter) w =0 and so AE= qv-
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 4 steps with 4 images

Blurred answer
Knowledge Booster
Thermochemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY