Consider the reaction below to answer the following

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Chapter1: Chemical Foundations
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4. Consider the reaction below to answer the following
questions
i. NaNH2 (1 mole)
III
Pd/CaCOz/PbO
Quinoline
CH3-C=CH
IV
Lindlars
ii. CH;CH,CH,Br
(1 mole)
catalyst
i) What are the products III and IV in the reaction sequence
above?
ii) Show the mechanism for the formation of product III.
5. Synthesize the following molecule from the ethyne as the
starting material. You may use any alkyl halide and any
inorganic reagent.
HC=CH
CH;CH=CHCH,CH,CH;
Br
H-C=C-H
CH3-CH,-ČHCH3
Starting
materials
6. Provide the missing products or reagents A, B and C in
the following reaction sequence.
В
NANH2
Li
CH;C=CH
А
CH3C=CCH,CH3
liq NH3
Transcribed Image Text:4. Consider the reaction below to answer the following questions i. NaNH2 (1 mole) III Pd/CaCOz/PbO Quinoline CH3-C=CH IV Lindlars ii. CH;CH,CH,Br (1 mole) catalyst i) What are the products III and IV in the reaction sequence above? ii) Show the mechanism for the formation of product III. 5. Synthesize the following molecule from the ethyne as the starting material. You may use any alkyl halide and any inorganic reagent. HC=CH CH;CH=CHCH,CH,CH; Br H-C=C-H CH3-CH,-ČHCH3 Starting materials 6. Provide the missing products or reagents A, B and C in the following reaction sequence. В NANH2 Li CH;C=CH А CH3C=CCH,CH3 liq NH3
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