Consider the peaks for pentafluorobenzene and benzene in the chromatogram shown below. The elution time of the unretained solute is 1.06 min. The open tubular column is 30.0 m in length and 0.530 mm in diameter, with a stationary phase 3.0 μm thick on the inner wall. (a) Find the adjusted retention times and capacity factors for both compounds; (b) Find the relative retention (also known as selectivity factor) between the two compounds; (c) Measuring W₁/2 on the chromatogram, find the number of plates (N₁ and N₂) and the plate height for these two compounds. (d) Measuring the width (w) at the baseline on the chromatogram, find the number of plates for these two compounds and compare to your answer for (c); (e) Using the width measurements from (c) to derive the baseline widths for the two compounds, find the resolution between the two peaks;
Consider the peaks for pentafluorobenzene and benzene in the chromatogram shown below. The elution time of the unretained solute is 1.06 min. The open tubular column is 30.0 m in length and 0.530 mm in diameter, with a stationary phase 3.0 μm thick on the inner wall. (a) Find the adjusted retention times and capacity factors for both compounds; (b) Find the relative retention (also known as selectivity factor) between the two compounds; (c) Measuring W₁/2 on the chromatogram, find the number of plates (N₁ and N₂) and the plate height for these two compounds. (d) Measuring the width (w) at the baseline on the chromatogram, find the number of plates for these two compounds and compare to your answer for (c); (e) Using the width measurements from (c) to derive the baseline widths for the two compounds, find the resolution between the two peaks;
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Related questions
Question
Answer the questions by using the given graph below
Expert Solution
Trending now
This is a popular solution!
Step by step
Solved in 10 steps
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY