Consider the para-substituted aromatic ketones, NO,CeH,COCH3 (p-nitroacetophenone) and CH30OC,H,COCH3(p-methoxyacetophenone).a. Which carbonyl compound is more stable?b. Which compound forms the higher percentage of hydrate at equilibrium?c. Which compound exhibits a carbonyl absorption at higher wavenumber in its IR spectrum? Explain your reasoning in eachpart.

The structure of p-nitro acetophenone is; The structure of p-methoxy acetophenone: Carbonyl…

Answered: Consider the para-substituted aromatic…

Chemistry

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ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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19. Substituted phenols show substituent effects similiar to substituted benzoic acids. Should the pKa of phenol A, one of the naturally occurring phenols called urushiols isolated from poison ivy, be higher or lower than the pKa of phenol (C6H5OH, pKa = 10)? Explain.
Why is it necessary to incorporate the benzyl group on the chloroamine used to convert B to C?
150% 5. Which type of spectroscopy (IR, 'H NMR, and/or 13C NMR) would be good to distinguish between benzonitrile and acetophenone? State what you would observe for each compound in each type of spectroscopy and whether that type of spectroscopy would be a good way to distinguish between the two compounds. Good way to distinguish? benzonitrile acetophenone IR 1H NMR 13C NMR 8.50 x 11.00 in
the epoxide shown will react in acidic methanol to generate which product. Select one: a. None of the choices are correct, the methoxy group will be on a different position. b. (1R,25)-1-Methoxy-1-phenyl-2-propanol X Oc. (1R,2R)-1-Methoxy-1-phenyl-2-propanol O d. (15,25)-1-Methoxy-1-phenyl-2-propanol Oe. (15,2R)-1-Methoxy-1-phenyl-2-propanol
Which of the following reagent best accomplish this transformation below? a. Li/NH3 b. H2SO4, H2O, HgSO4 c. BH3, THF d. potassium permanganate
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2. If the bromination of 4 mmol of 4-methylbenzoic acid with 4 mmol of N-bromosuccinimide resulted in 525 mg of 4-bromomethylbenzoic acid, what is the yield of the reaction? 61% 23% C. 97% d. 57% a. b.
A student mixes benzaldehyde with an unknown symmetrical ketone, compound C, in an aqueous sodium hydroxide solution and produces compound D.Based on the 1H NMR of compound D, shown below, predict the structure of compound
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