Consider the following tetra-substituted cyclohexane and the values from Table 4.8: TABLE 4.8 1,3-DIAXIAL INTERACTIONS FOR SEVERAL COMMON SUBSTITUENT SUBSTITUENT 1,3-DIAXIAL INTERACTIONS EQUATORIAL-AXIAL RA -a -OH -CH3 -CH₂ CH3 (KJ/MOL) 2.0 4.2 7.6 8.0 9.2 22.8 -CH(CH3)2 -C(CH3)3 Select both chair conformations of this compound. Et OH OH Y 금 Et Et -OH OH YFI (AT EQUILIBRIUM) 70:30 83:17 95:5 96:4 OH 97:3 9999:1
Consider the following tetra-substituted cyclohexane and the values from Table 4.8: TABLE 4.8 1,3-DIAXIAL INTERACTIONS FOR SEVERAL COMMON SUBSTITUENT SUBSTITUENT 1,3-DIAXIAL INTERACTIONS EQUATORIAL-AXIAL RA -a -OH -CH3 -CH₂ CH3 (KJ/MOL) 2.0 4.2 7.6 8.0 9.2 22.8 -CH(CH3)2 -C(CH3)3 Select both chair conformations of this compound. Et OH OH Y 금 Et Et -OH OH YFI (AT EQUILIBRIUM) 70:30 83:17 95:5 96:4 OH 97:3 9999:1
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![Consider the following tetra-substituted
cyclohexane and the values from Table 4.8:
TABLE 4.8
1,3-DIAXIAL INTERACTIONS FOR SEVERAL COMMON SUBSTITUENTS
SUBSTITUENT 1,3-DIAXIAL INTERACTIONS EQUATORIAL-AXIAL RATIO
-Cl
-OH
-CH3
-CH₂ CH3
(KJ/MOL)
2.0
CI-
4.2
7.6
8.0
Y
-CH(CH3)2
-C(CH3)3
Select both chair conformations of this
compound.
Et
#
9.2
22.8
OH
Et
OH
Et
OH
OH
Et
(AT EQUILIBRIUM)
70:30
83:17
95:5
96:4
97:3
9999:1
OH](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F071f09c0-a518-4766-b602-5412bf2a97d0%2F0254d19b-ef26-4b15-b128-723ce7990485%2Flo8eg6_processed.png&w=3840&q=75)
Transcribed Image Text:Consider the following tetra-substituted
cyclohexane and the values from Table 4.8:
TABLE 4.8
1,3-DIAXIAL INTERACTIONS FOR SEVERAL COMMON SUBSTITUENTS
SUBSTITUENT 1,3-DIAXIAL INTERACTIONS EQUATORIAL-AXIAL RATIO
-Cl
-OH
-CH3
-CH₂ CH3
(KJ/MOL)
2.0
CI-
4.2
7.6
8.0
Y
-CH(CH3)2
-C(CH3)3
Select both chair conformations of this
compound.
Et
#
9.2
22.8
OH
Et
OH
Et
OH
OH
Et
(AT EQUILIBRIUM)
70:30
83:17
95:5
96:4
97:3
9999:1
OH
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