Consider the following reaction of methane with molecular chlorine: CH4 (g) + Cl2 (g)→ CH3C1 (g) + HC1 (g) Experimental studies have shown that the rate law for this reaction is one-half order w respect to Cl2. Is the following mechanism consistent with this behavior? Ch 2 Cl . Cl• + CH4 HCI + CH, • CH,. + Cl2 CH3C1+ Cl. Cl• + Cl. Ch L[Cl,] k. d[HCl] Prove that rate law expression dt [CH4].

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Consider the following reaction of methane with molecular chlorine:
CH4 (g) + C2 (g) CH;C1 (g) + HC1 (g)
Experimental studies have shown that the rate law for this reaction is one-half order with
respect to Cl2. Is the following mechanism consistent with this behavior?
Cl2 2Cl.
Cl• + CH4
HCI+ CH, •
CH3
+ Cl2
CH3CI+ Cl.
Cl• + Cl.-
Ch
d[HCl]
[Cl,]
k4
dt
Prove that rate law expression
[CH4].
Transcribed Image Text:Consider the following reaction of methane with molecular chlorine: CH4 (g) + C2 (g) CH;C1 (g) + HC1 (g) Experimental studies have shown that the rate law for this reaction is one-half order with respect to Cl2. Is the following mechanism consistent with this behavior? Cl2 2Cl. Cl• + CH4 HCI+ CH, • CH3 + Cl2 CH3CI+ Cl. Cl• + Cl.- Ch d[HCl] [Cl,] k4 dt Prove that rate law expression [CH4].
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