Consider the following equilibrium: 2NOC1 (g) 2NO(g) + Cl₂ (g) AG = 41. kJ Now suppose a reaction vessel is filled with 2.53 atm of nitrosyl chloride (NOCI) and 2.19 atm of chlorine (C1₂) at 869. °C. Answer the following questions about this system: L Under these conditions, will the pressure of NOCI tend to rise or fall? Is it possible to reverse this tendency by adding NO? In other words, if you said the pressure of NOCI will tend to rise, can that be changed to a tendency to fall by adding NO? Similarly, if you said the pressure of NOCI will tend to fall, can that be changed to a tendency to rise by adding NO? If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO needed to reverse it. Round your answer to 2 significant digits. rise O fall Oyes Ono atm 0.2 X $

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### Chemical Equilibrium Problem

Consider the following equilibrium reaction:

\[ \text{2NOCl (g)} \rightleftharpoons \text{2NO (g)} + \text{Cl}_2 \text{(g)} \quad \Delta G^\circ = 41.1 \text{ kJ} \]

Now suppose a reaction vessel is filled with 2.53 atm of nitrosyl chloride (NOCl) and 2.19 atm of chlorine (Cl₂) at 869 °C. Answer the following questions about this system:

1. Under these conditions, will the pressure of NOCl tend to rise or fall?
    - ☐ rise
    - ☐ fall

2. Is it possible to reverse this tendency by adding NO?
   In other words, if you said the pressure of NOCl will tend to rise, can that be changed to a tendency to fall by adding NO? Similarly, if you said the pressure of NOCl will tend to fall, can that be changed to a tendency to rise by adding NO?
    - ☐ yes
    - ☐ no

3. If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO needed to reverse it.
    - \[ \_\_\_\_\_\_\_\_\_\_ \] atm  
    (Round your answer to 2 significant digits.)

*[Note: There is a refresh button and zoom buttons beside the third question likely for resetting or preview purposes in an online interface.]*
Transcribed Image Text:### Chemical Equilibrium Problem Consider the following equilibrium reaction: \[ \text{2NOCl (g)} \rightleftharpoons \text{2NO (g)} + \text{Cl}_2 \text{(g)} \quad \Delta G^\circ = 41.1 \text{ kJ} \] Now suppose a reaction vessel is filled with 2.53 atm of nitrosyl chloride (NOCl) and 2.19 atm of chlorine (Cl₂) at 869 °C. Answer the following questions about this system: 1. Under these conditions, will the pressure of NOCl tend to rise or fall? - ☐ rise - ☐ fall 2. Is it possible to reverse this tendency by adding NO? In other words, if you said the pressure of NOCl will tend to rise, can that be changed to a tendency to fall by adding NO? Similarly, if you said the pressure of NOCl will tend to fall, can that be changed to a tendency to rise by adding NO? - ☐ yes - ☐ no 3. If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO needed to reverse it. - \[ \_\_\_\_\_\_\_\_\_\_ \] atm (Round your answer to 2 significant digits.) *[Note: There is a refresh button and zoom buttons beside the third question likely for resetting or preview purposes in an online interface.]*
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