Consider the following equilibrium: 2NOC1 (g) 2NO (g) + Cl, (g) AG°=41. kJ Now suppose a reaction vessel is filled with 9.93 atm of nitrosyl chloride (NOCI) and 6.60 atm of chlorine (Cl,) at 839. °C. Answer the following questions about this system: O rise Under these conditions, will the pressure of CI, tend to rise or fall? fall Is it possible to reverse this tendency by adding NO? In other words, if you said the pressure of CI, will tend to rise, can that yes be changed to a tendency to fall by adding NO? Similarly, if you said the pressure of CI, will tend to fall, can that be changed to a tendency to rise no '2 by adding NO? If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO needed to reverse it. D atm Round your answer to 2 significant digits.

Consider the following equilibrium: 2NOC1 (g) 2NO (g) + Cl, (g) AG°=41. kJ Now suppose a reaction vessel is filled with 9.93 atm of nitrosyl chloride (NOCI) and 6.60 atm of chlorine (Cl,) at 839. °C. Answer the following questions about this system: O rise Under these conditions, will the pressure of CI, tend to rise or fall? fall Is it possible to reverse this tendency by adding NO? In other words, if you said the pressure of CI, will tend to rise, can that yes be changed to a tendency to fall by adding NO? Similarly, if you said the pressure of CI, will tend to fall, can that be changed to a tendency to rise no '2 by adding NO? If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO needed to reverse it. D atm Round your answer to 2 significant digits.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Carbon tetrachloride can be produced by the following reaction: CS2(g)+3 Cl2 (g)S, Cla (s) +CCL, (g) Suppose 1.20 mol of CS2 and 3.60 mol of Cl2 were placed in a 1.00-L flask at an unknown temperature. After equilibrium has been achieved, the mixture contains 0.61 mol of CC14. Calculate Kc at the unknown temperature.
Consider the following equilibrium: 2NH, (g) – N, (g) + 3H, (g) AG° = 34. kJ Now suppose a reaction vessel is filled with 5.02 atm of ammonia (NH,) and 9.40 atm of nitrogen (N,) at 159. °C. Answer the following questions about this system: rise Under these conditions, will the pressure of N, tend to rise or fall? fall Is it possible to reverse this tendency adding H2? In other words, if you said the pressure of N, will tend to rise, can that be yes changed to a tendency to fall by adding H,? Similarly, if you said the no pressure of N, will tend to fall, can that be changed to a tendency to rise by adding H2? If you said the tendency can be reversed in the second question, calculate the minimum pressure of H, needed to reverse it. atm Round your answer to 2 significant digits.
Consider the following equilibrium: N2O4(g) 2NO2 (g) AG = 5.4 kJ Now suppose a reaction vessel is filled with 2.78 atm of dinitrogen tetroxide (N204) at 710. °C. Answer the following questions about this system: rise x10 fall Under these conditions, will the pressure of N2O4 tend to rise or fall? Is it possible to reverse this tendency by adding NO2? In other words, if you said the pressure of N2O4 will tend to rise, can that be changed to a tendency to fall by adding NO2? Similarly, if you said the pressure of N2O4 will tend to fall, can that be changed to a tendency to rise by adding NO2? If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO2 needed to reverse it. Round your answer to 2 significant digits. yes no ☐ atm X S
Consider the following equilibrium: 2NOC1 (g) → 2NO(g) + Cl₂ (g) AG = 41. kJ Now suppose a reaction vessel is filled with 8.30 atm of nitrosyl chloride (NOC1) and 5.80 atm of chlorine (C1₂) at 878. °C. Answer the following questions about this system: Under these conditions, will the pressure of Cl₂ tend to rise or fall? Is it possible to reverse this tendency by adding NO? In other words, if you said the pressure of Cl₂ will tend to rise, can that be changed to a tendency to fall by adding NO? Similarly, if you said the pressure of Cl₂ will tend to fall, can that be changed to a tendency to rise by adding NO? If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO needed to reverse it. Round your answer to 2 significant digits. оо rise fall yes no 0 atm x10 X Ś
4. Toluene, C;H8(1), is an important organic solvent. It is made industrially from methylcyclohexane, C,H14(g): C,H14(g) + heat ? 2C;H8(1) + 3H2(g) State three different changes to an equilibrium mixture of these reacting gases that would shift the reaction toward greater production of toluene. State and explain each change.
Consider the following equilibrium: N,0, (g) = 2NO, (3) AG' = 5.4 kJ Now suppose a reaction vessel is filled with 0.496 atm of nitrogen dioxide (NO,) at 137. °C. Answer the following questions about this system: O rise Under these conditions, will the pressure of NO, tend to rise or fall? O fall Is it possible to reverse this tendency by adding N,O,? In other words, if you said the pressure of NO, will tend to rise, can that O yes be changed to a tendency to fall by adding N,04? Similarly, if you said O no the pressure of NO, will tend to fall, can that be changed to a tendency to rise by adding N,0,? If you said the tendency can be reversed in the second question, calculate the minimum pressure of N,0, needed to reverse it. O atm Round your answer to 2 significant digits.
Consider the following equilibrium: 2NH3(g) = N₂ (g) + 3H₂(g) 2 AG = 34. kJ Now suppose a reaction vessel is filled with 7.87 atm of ammonia (NH3) and 1.17 atm of hydrogen (H₂) at 448. °C. Answer the following questions about this system: Under these conditions, will the pressure of NH3 tend to rise or fall? Is it possible to reverse this tendency by adding N₂? In other words, if you said the pressure of NH3 will tend to rise, can that be changed to a tendency to fall by adding N₂? Similarly, if you said the pressure of NH3 will tend to fall, can that be changed to a tendency to rise by adding N₂? If you said the tendency can be reversed in the second question, calculate the minimum pressure of N₂ needed to reverse it. Round your answer to 2 significant digits. rise fall yes no atm x10 X 5
Consider the following equilibrium: 2NO(g) + Cl₂ (g) 2NOCI (g) AG=-41. kJ Now suppose a reaction vessel is filled with 1.55 atm of chlorine (C1₂). about this system: T Under these conditions, will the pressure of NOCI tend to rise or fall? Is it possible to reverse this tendency by adding NO? In other words, if you said the pressure of NOC1 will tend to rise, can that be changed to a tendency to fall by adding NO? Similarly, if said the pressure of NOCI will tend to fall, can that be changed to a tendency to rise by adding NO? If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO needed to reverse it. Round your answer to 2 significant digits. and 4.77 atm of nitrosyl chloride (NOCI) at 683. °C. Answer the following questions Orise Ofall yes Ono atm O x10 X S
Consider the following equilibrium: 2NH3(g) → N₂(g) + 3H₂(g) AG = 34. kJ Now suppose a reaction vessel is filled with 6.39 atm of ammonia (NH3) and 0.200 atm of hydrogen (H₂) at 206. °C. Answer the following questions about this system: Under these conditions, will the pressure of NH3 tend to rise or fall? Is it possible to reverse this tendency by adding N₂? In other words, if you said the pressure of NH3 will tend to rise, can that be changed to a tendency to fall by adding N₂? Similarly, if you said the pressure of NH3 will tend to fall, can that be changed to a tendency to rise by adding N₂? If you said the tendency can be reversed in the second question, calculate the minimum pressure of N₂ needed to reverse it. Round your answer to 2 significant digits. OO U rise fall yes no atm x10 X Ś
Nitrogen 2NF3(g)->N2(g) + 3F2(g) When 3.15 mol of NF3 is placed in a 3.00-L container and allowed to come to equilibrium at 900 K, the mixture is found to contain 0.0563 mol of N2. What is the value of K, at this temperature? (R = 0.0821 L'atm-mol¹ K¹). (Hint: Solve for Kc first, then calculate Kp) 4.43 x 10-7 1.8 x 102 1.11 x 10-5 191 x 103 1.07 x 10-5
Consider the following equilibrium: N₂ (g) + 3H₂(g) → 2NH3(g) AG = -34. KJ Now suppose a reaction vessel is filled with 3.40 atm of nitrogen (N₂) and 4.50 atm of ammonia (NH3) at 250. °C. Answer the following questions about this system: Under these conditions, will the pressure of NH3 tend to rise or fall? Is it possible to reverse this tendency by adding H₂? In other words, if you said the pressure of NH3 will tend to rise, can that be changed to a tendency to fall by adding H₂? Similarly, if you said the pressure of NH3 will tend to fall, can that be changed to a tendency to rise by adding H₂? If you said the tendency can be reversed in the second question, calculate the minimum pressure of H₂ needed to reverse it. Round your answer to 2 significant digits. OO rise fall yes no atm ☐x10 X Ś