Consider the following data on some weak acids and weak bases: formula hydrocyanic acid HCN name nitrous acid acid solution 0.1 M NaCN 0.1 M NaNO3 0.1 M NH4CI 0.1 M KNO₂ Ka 4.9 × 10 HNO₂ 4.5× 10 pH 10 Use this data to rank the following solutions in order of increasing pH. In other words, select a '1' next to the solution that will have the lowest pH, a '2' next to the solution that will have the next lowest pH, and so on. ✓ choose one 3 1 (lowest) 2 3 4 (highest) choose one base name formula NH3 aniline C6H5NH₂ 4.3 × 10 10 Kb ammonia 1.8 x 10 -5

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### Weak Acids and Weak Bases Data

#### Acids:
| Name               | Formula | \( K_a \)         |
|--------------------|---------|-------------------|
| Hydrocyanic acid   | HCN     | \( 4.9 \times 10^{-10} \) |
| Nitrous acid       | HNO\(_2\) | \( 4.5 \times 10^{-4} \)  |

#### Bases:
| Name    | Formula    | \( K_b \)         |
|---------|------------|-------------------|
| Ammonia | NH\(_3\)   | \( 1.8 \times 10^{-5} \)  |
| Aniline | C\(_6\)H\(_5\)NH\(_2\) | \( 4.3 \times 10^{-10} \) |

### Task:

Use the data provided to rank the following solutions in order of increasing pH. Select a '1' next to the solution with the lowest pH, a '2' for the next, and so forth.

#### Solutions to Rank:
| Solution          | pH Ranking           |
|-------------------|----------------------|
| 0.1 M NaCN        | [Select Rank]        |
| 0.1 M NaNO\(_3\)  | [Select Rank]        |
| 0.1 M NH\(_4\)Cl  | [Select Rank]        |
| 0.1 M KNO\(_2\)   | [Select Rank]        |

### Instructions:

For each solution, consider the acidic or basic nature of the ions present, and how they dissociate in water to affect the pH level.
Transcribed Image Text:### Weak Acids and Weak Bases Data #### Acids: | Name | Formula | \( K_a \) | |--------------------|---------|-------------------| | Hydrocyanic acid | HCN | \( 4.9 \times 10^{-10} \) | | Nitrous acid | HNO\(_2\) | \( 4.5 \times 10^{-4} \) | #### Bases: | Name | Formula | \( K_b \) | |---------|------------|-------------------| | Ammonia | NH\(_3\) | \( 1.8 \times 10^{-5} \) | | Aniline | C\(_6\)H\(_5\)NH\(_2\) | \( 4.3 \times 10^{-10} \) | ### Task: Use the data provided to rank the following solutions in order of increasing pH. Select a '1' next to the solution with the lowest pH, a '2' for the next, and so forth. #### Solutions to Rank: | Solution | pH Ranking | |-------------------|----------------------| | 0.1 M NaCN | [Select Rank] | | 0.1 M NaNO\(_3\) | [Select Rank] | | 0.1 M NH\(_4\)Cl | [Select Rank] | | 0.1 M KNO\(_2\) | [Select Rank] | ### Instructions: For each solution, consider the acidic or basic nature of the ions present, and how they dissociate in water to affect the pH level.
Expert Solution
Step 1: Concepts required to solve the given problem!

Answer:

Three concepts will be required to arrange the given solutions in increasing order of pH:

  1. Salt of strong acid and weak base produces weakly acidic solution and salt of weak acid and strong base produces weakly basic solution due to hydrolysis.
  2. Salt of strong acid and strong base always produces a neutral solution because none of its ions can go under hydrolysis.
  3. conjugate base of strong acid will be the weaker base and conjugate acid of strong base will be the weaker acid and vice versa.


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