Consider the following cell diagram: Mg(s) | MgSO4(0.40 M) || NiSO4(0.60 M) | Ni(s) Calculate the cell voltage at 25°C. How does the cell voltage change when (a) [Mg2+] is decreased by a factor of 4 and (b) [Ni2+] is decreased by a factor of 3?

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Consider the following cell diagram:

Mg(s) | MgSO4(0.40 M) || NiSO4(0.60 M) | Ni(s)

Calculate the cell voltage at 25°C. How does the cell voltage change when (a) [Mg2+] is decreased by a factor of 4 and (b) [Ni2+] is decreased by a factor of 3?

 

Activities and Assessments:
1. What is the emf of a galvanic cell consisting of a Cd²+/Cd half-cell and a Pt/H* /H2 half-
cell if [Cd2+] = 0.20 M, [H*] = 0.16 M , and PH, = 0.80 atm?
2. Consider the cell diagram Mg(s)|M9SO,(0.40 M)||NiS0,(0.60 M)|Ni(s). Calculate the cell
voltage at 25°C. How does the cell voltage change when:
a. [Mg2+] is decreased by a factor of 4
b. [Ni2+] is decreased by a factor of 3
3. Consider the reaction at 25°C
Mn02(s) + 4 Haq) + 2 Brīag) → Mnaq) + Br2(1) + 2H20(1)
At what pH is the voltage zero if all other species are at standard conditions?
Transcribed Image Text:Activities and Assessments: 1. What is the emf of a galvanic cell consisting of a Cd²+/Cd half-cell and a Pt/H* /H2 half- cell if [Cd2+] = 0.20 M, [H*] = 0.16 M , and PH, = 0.80 atm? 2. Consider the cell diagram Mg(s)|M9SO,(0.40 M)||NiS0,(0.60 M)|Ni(s). Calculate the cell voltage at 25°C. How does the cell voltage change when: a. [Mg2+] is decreased by a factor of 4 b. [Ni2+] is decreased by a factor of 3 3. Consider the reaction at 25°C Mn02(s) + 4 Haq) + 2 Brīag) → Mnaq) + Br2(1) + 2H20(1) At what pH is the voltage zero if all other species are at standard conditions?
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