Consider the element vanadium (Z=23)a) There is a line in the vanadium spectrum at 318.5nm.i. What is the frequency of the line?ii. What is the energy difference between the two levels responsible for this line in kJ per mole?iv. The ionization energy of vanadium from the ground state is 650.2 kJ/mol. Assume that the transition in (3) is from the ground state to an excited state. If that is the case, calculate the ionization energy from the excited state.

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Quantum Chemistry

Quantum chemistry deals with the properties of chemical systems and their reactions. The branch of chemistry which is more concerned with quantum chemistry is physical chemistry. It is a more sophisticated field of theoretical physics which is concerned towards the application of physical concepts towards various chemical aspects such as, formation of atoms, chemical structure descriptions, chemical bond strength, hybridization, conjugation etc. Quantum chemistry mainly studies the various states i.e., ground state, excited state, transition states of the individual atoms or molecules taking place during any chemical reaction. The laws of motion explained by various scientists, which are termed as “classical mechanics” were not acceptable in terms of electrons, protons, atoms, light etc. Thus, a new theory named “quantum mechanics” emerged to understand the basic framework of various atomic and subatomic particles.