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Consider the Diels-Alder cycloaddition-based synthesis of F and answer sections (1)- (). COCI NMe NHME Identity an acyclic amide G which undergoes Diels-Alder cycloaddition to form F. (1) Suggest a reaction mechanism for the conversion of G into F, draw its alternative diastereomer and explain whether the product Fis formed via the exo or the endo transition state. (H) Disconnect amide G. Identily the resultant synthons and describe how they correspond to synthetic equivalents H and J.

Consider the Diels-Alder cycloaddition-based synthesis of F and answer sections (1)- (). COCI NMe NHME Identity an acyclic amide G which undergoes Diels-Alder cycloaddition to form F. (1) Suggest a reaction mechanism for the conversion of G into F, draw its alternative diastereomer and explain whether the product Fis formed via the exo or the endo transition state. (H) Disconnect amide G. Identily the resultant synthons and describe how they correspond to synthetic equivalents H and J.

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Consider the Diels-Alder cycloaddition-based synthesis of F and answer sections (1)- (). COCI NMe NHMe () Identity an acyclic amide G which undergoes Diels-Alder cycloaddition to form F. (1) Suggest a reaction mechanism for the conversion of G into F, draw its alternative diastereomer and explain whether the product Fis formed via the exo or the endo transition state. (H) Disconnect amide G. Identily the resultant synthons and describe how they correspond to synthetic equivalents H and J.
Transcribed Image Text:Consider the Diels-Alder cycloaddition-based synthesis of F and answer sections (1)- (). COCI NMe NHMe () Identity an acyclic amide G which undergoes Diels-Alder cycloaddition to form F. (1) Suggest a reaction mechanism for the conversion of G into F, draw its alternative diastereomer and explain whether the product Fis formed via the exo or the endo transition state. (H) Disconnect amide G. Identily the resultant synthons and describe how they correspond to synthetic equivalents H and J.
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