Consider how to prepare a buffer solution with pH = 3.21 (using one of the weak acid/conjugate base systems shown here) by combining 1.00 L of a 0.430-M solution of weak acid with 0.307 M potassium hydroxide. Weak Acid Conjugate Base HNO2 HCIO HCN NO₂™ CIO CN Ka 4.5 x 10-4 3.5 x 10-8 4.0 x 10-10 pka 3.35 7.46 9.40 How many L of the potassium hydroxide solution would have to be added to the acid solution of your choice?
Consider how to prepare a buffer solution with pH = 3.21 (using one of the weak acid/conjugate base systems shown here) by combining 1.00 L of a 0.430-M solution of weak acid with 0.307 M potassium hydroxide. Weak Acid Conjugate Base HNO2 HCIO HCN NO₂™ CIO CN Ka 4.5 x 10-4 3.5 x 10-8 4.0 x 10-10 pka 3.35 7.46 9.40 How many L of the potassium hydroxide solution would have to be added to the acid solution of your choice?
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Related questions
Question

Transcribed Image Text:To prepare a buffer solution with a pH of 3.21, using one of the weak acid/conjugate base systems listed, you combine 1.00 L of a 0.430 M solution of weak acid with a 0.307 M potassium hydroxide solution.
### Weak Acid and Conjugate Base Systems
- **HNO₂ / NO₂⁻**
- \( K_a = 4.5 \times 10^{-4} \)
- \( pK_a = 3.35 \)
- **HClO / ClO⁻**
- \( K_a = 3.5 \times 10^{-8} \)
- \( pK_a = 7.46 \)
- **HCN / CN⁻**
- \( K_a = 4.0 \times 10^{-10} \)
- \( pK_a = 9.40 \)
### Task
Calculate the volume in liters of the potassium hydroxide solution required to achieve the desired buffer pH with your chosen weak acid solution.
Expert Solution

Step 1: Defining buffer solution
Answer:
Buffer solution is a type of solution that resists the change in its pH on adding small quantity of acid or base. The solution of weak acid and its conjugate base can act like a buffer solution.
Trending now
This is a popular solution!
Step by step
Solved in 6 steps with 6 images

Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you

Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning

Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education

Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning

Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning

Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education

Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning

Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education

Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning

Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY