Consider how to prepare a buffer solution with pH = 3.21 (using one of the weak acid/conjugate base systems shown here) by combining 1.00 L of a 0.430-M solution of weak acid with 0.307 M potassium hydroxide. Weak Acid Conjugate Base HNO2 HCIO HCN NO₂™ CIO CN Ka 4.5 x 10-4 3.5 x 10-8 4.0 x 10-10 pka 3.35 7.46 9.40 How many L of the potassium hydroxide solution would have to be added to the acid solution of your choice?
Consider how to prepare a buffer solution with pH = 3.21 (using one of the weak acid/conjugate base systems shown here) by combining 1.00 L of a 0.430-M solution of weak acid with 0.307 M potassium hydroxide. Weak Acid Conjugate Base HNO2 HCIO HCN NO₂™ CIO CN Ka 4.5 x 10-4 3.5 x 10-8 4.0 x 10-10 pka 3.35 7.46 9.40 How many L of the potassium hydroxide solution would have to be added to the acid solution of your choice?
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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![To prepare a buffer solution with a pH of 3.21, using one of the weak acid/conjugate base systems listed, you combine 1.00 L of a 0.430 M solution of weak acid with a 0.307 M potassium hydroxide solution.
### Weak Acid and Conjugate Base Systems
- **HNO₂ / NO₂⁻**
- \( K_a = 4.5 \times 10^{-4} \)
- \( pK_a = 3.35 \)
- **HClO / ClO⁻**
- \( K_a = 3.5 \times 10^{-8} \)
- \( pK_a = 7.46 \)
- **HCN / CN⁻**
- \( K_a = 4.0 \times 10^{-10} \)
- \( pK_a = 9.40 \)
### Task
Calculate the volume in liters of the potassium hydroxide solution required to achieve the desired buffer pH with your chosen weak acid solution.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fd295e1c3-483d-49b7-8dbf-fcde864060f6%2F25c72f6a-da2f-4ec8-a925-5466d5cb585f%2Fw3mjtj8_processed.png&w=3840&q=75)
Transcribed Image Text:To prepare a buffer solution with a pH of 3.21, using one of the weak acid/conjugate base systems listed, you combine 1.00 L of a 0.430 M solution of weak acid with a 0.307 M potassium hydroxide solution.
### Weak Acid and Conjugate Base Systems
- **HNO₂ / NO₂⁻**
- \( K_a = 4.5 \times 10^{-4} \)
- \( pK_a = 3.35 \)
- **HClO / ClO⁻**
- \( K_a = 3.5 \times 10^{-8} \)
- \( pK_a = 7.46 \)
- **HCN / CN⁻**
- \( K_a = 4.0 \times 10^{-10} \)
- \( pK_a = 9.40 \)
### Task
Calculate the volume in liters of the potassium hydroxide solution required to achieve the desired buffer pH with your chosen weak acid solution.
Expert Solution
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Step 1: Defining buffer solution
Answer:
Buffer solution is a type of solution that resists the change in its pH on adding small quantity of acid or base. The solution of weak acid and its conjugate base can act like a buffer solution.
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