Consider an LMCT complex of the form, [MoO4]n+.  Which of the following metal centers will have the highest d orbital energy? Group of answer choices Mo2+ Mo6+ Mo3+ Mo4+

Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter19: Transitition Metals, Coordination Chemistry And Metallurgy
Section: Chapter Questions
Problem 19.45QE: For each d electron configuration, state the number of unpaired electrons expected in octahedral...
icon
Related questions
Question
Consider an LMCT complex of the form, [MoO4]n+.  Which of the following metal centers will have the highest d orbital energy?
Group of answer choices
Mo2+
Mo6+
Mo3+
Mo4+
Expert Solution
Step 1 Theory

In LMCT, Increase in oxidation state of metal ion   decreases the energy of d-orbital of metal center. 

Higher the oxidation state/number, lower will be the energy of d-orbital.

steps

Step by step

Solved in 2 steps

Blurred answer
Knowledge Booster
Atomic Structure and Spectra
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Chemistry: Principles and Practice
Chemistry: Principles and Practice
Chemistry
ISBN:
9780534420123
Author:
Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:
Cengage Learning
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry: An Atoms First Approach
Chemistry: An Atoms First Approach
Chemistry
ISBN:
9781305079243
Author:
Steven S. Zumdahl, Susan A. Zumdahl
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781133611097
Author:
Steven S. Zumdahl
Publisher:
Cengage Learning
Principles of Modern Chemistry
Principles of Modern Chemistry
Chemistry
ISBN:
9781305079113
Author:
David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:
Cengage Learning