Consider a fuel cell that uses the reaction of ethanol with oxygen to produce electricity. CH, CH,OH(1) + 3 0,(g) → 2 CO,(g) + 3 H,O(1) Use thermodynamic data to determine the value of E for this cell at 25 °C. Eall = V 'cell

Consider a fuel cell that uses the reaction of ethanol with oxygen to produce electricity. CH, CH,OH(1) + 3 0,(g) → 2 CO,(g) + 3 H,O(1) Use thermodynamic data to determine the value of E for this cell at 25 °C. Eall = V 'cell

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

See similar textbooks

Similar questions

A certain metal M forms a soluble nitrate salt M(NO3)2. Suppose the left half cell of a galvanic cell apparatus is filled with a 1.50 M solution of M(NO3)₂ and the right half cell with a 15.0 mM solution of the same substance. Electrodes made of M are dipped into both solutions and a voltmeter is connected between them. The temperature of the apparatus is held constant at 30.0 °C. Which electrode will be positive? What voltage will the voltmeter show? Assume its positive lead is connected to the positive electrode. 0 Be sure your answer has a unit symbol, if necessary, and round it to 2 significant digits. left right X Ś ?
A certain metal M forms a soluble nitrate salt MNO,. Suppose the left half cell of a galvanic cell apparatus is filled with a 3.50 M solution of MNO, and the right half cell with a 17.5 mM solution of the same substance. Electrodes made of M are dipped into both solutions and a voltmeter is connected between them. The temperature of the apparatus is held constant at 30.0 °C. left x10 Which electrode will be positive? right What voltage will the voltmeter show? Assume its positive lead is connected to the positive electrode. Be sure your answer has a unit symbol, if necessary, and round it to 2 significant digits.
Please don't provide handwritten solution
Consider the cell below at standard conditions: Zn(s) | Zn 2+ (aq) || Fe 2+ (aq) | Fe(s)Calculate the value of ΔG° for the reaction that occurs if the value of E° cell = 0.32 V for this cell.
A certain metal M forms a soluble sulfate salt M₂SO4. Suppose the left half cell of a galvanic cell apparatus is filled with a 2.00 M solution of M₂SO4 and the right half cell with a 10.0 mM solution of the same substance. Electrodes made M are dipped into both solutions and a voltmeter is connected between them. The temperature of the apparatus is held constant at 35.0 °C. Which electrode will be positive? What voltage will the voltmeter show? Assume its positive lead is connected to the positive electrode. Be sure your answer has a unit symbol, if necessary, and round it to 2 significant digits. V left right x10 X T
Consider a voltaic cell in which the reaction is Zn (s) + 2H+ (aq) → Zn2+ (aq) + H2 (g) It is found that the cell voltage is +0.530 V when [Zn2+] = 1.0 M, PH2 = 1.0 atm. What must be the concentration of H+ in the cell? (Use the following information) (Show your work) 2H+ (aq) + 2e- → H2 (g) Eºred = 0.000 V Zn2+ (aq) + 2e- → Zn(s) Eºred = -0.762 V
Questions 20 and 21 refer to the following information. Galvanic Cell Cell Diagram E°cell (Volts) Mg | Mg2(1.0 M) || Pb*2(1.0 M) | Pb 1 2.24 Zn | Zn(1.0 M) || Pb*2(1.0 M) | Pb 2 0.63 Mg | Mg*(1.0 M) || Zn*2(1.0 M) | Zn 3 The chemical reaction occurring in first galvanic cell is: Mg + Pb*2 → Mg+2 + Pb 21. If the concentration of Mg+2 is changed from 1.0 M to 3.0 M in the galvanic cells above, what will happen to the observed cell voltages in galvanic cells 1 and 3? (A) The voltage in both galvanic cells 1 and 3 will increase. (B) The voltage will decrease in both galvanic cells 1 and 3. (C) The voltage in galvanic cell 1 will increase and will decrease in galvanic cell 3 (D) The voltage in galvanic cell 3 will increase and will decrease in galvanic cell 1. 22. Consider a voltaic cell based on these half-cells. Ag (aq) +e → Ag/s) Cd (aq) + 2e → Cd¢s) E* = +0.80 V E = -0.40 V Identify the anode and give the voltage of this cell under standard conditions. (A) Ag; Ecell = 0.40 V (B) Ag;…
Consider the following voltaic cellat 25°C: Al(s) | Al3*(0.20 M, aq) || Al3+(0.75 M, aq) | Al(s) If the standard reduction potential for the Al3+(aq) /Al(s) redox couple is -1.66 V, what is the overall cell reaction and the cell potential of the voltaic cell shown above? (Reference the cell as written above.) The overall cell reaction is Al3+(0.75 M, aq) AIS*(0.20 M, ag) and E°cell = +0.0113 V. There is no overall cell reaction and E°cell = 0.00 V. The overall cell reaction is Al3+(0.20 M, aq) Als*(0.75 M, aq) and E°cell = +0.0113 V. The overall cell reaction is Al3+(0.20 M, aq) →A13+(0.75 M, ag) and E°cell| = -0.0113 V. The overall cell reaction is Al3*(0.75 M, aq) →AI3*(0.20 M, aq) and E°cell = -0.0113 V. None of these
A certain metal M forms a soluble nitrate salt MNO3. Suppose the left half cell of a galvanic cell apparatus is filled with a 15.0 mM solution of MNO3 and the right half cell with a 3.00 M solution of the same substance. Electrodes made of M are dipped into both solutions and a voltmeter is connected between them. The temperature of the apparatus is held constant at 30.0 °C. Which electrode will be positive? What voltage will the voltmeter show? Assume its positive lead is connected to the positive electrode. Be sure your answer has a unit symbol, if necessary, and round it to 2 significant digits. O left 0 right x10 X
A certain metal M forms a soluble nitrate salt M(NO3). Suppose the left half cell of a galvanic cell apparatus is filled with a 4.00 M solution of M(NO3), and the right half cell with a 200. mM solution of the same substance. Electrodes made of M are dipped into both solutions and a voltmeter is connected between them. The temperature of the apparatus is held constant at 30.0 °C. Which electrode will be positive? What voltage will the voltmeter show? Assume its positive lead is connected to the positive electrode. Be sure your answer has a unit symbol, if necessary, and round it to 2 significant digits. left ☐ x10 right
A certain metal M forms a soluble sulfate salt M, SO4. Suppose the left half cell of a galvanic cell apparatus is filled with a 250. mM solution of M,SO, and the right half cell with a 2.50 M solution of the same substance. Electrodes made of M are dipped into both solutions and a voltmeter is connected between them. The temperature of the apparatus is held constant at 35.0 °C. left Which electrode will be positive? Ox10 right ? What voltage will the voltmeter show? Assume its positive lead is connected to the positive electrode. Be sure your answer has a unit symbol, if necessary, and round it to 2 significant digits.
A certain metal M forms a soluble sulfate salt M₂SO4. Suppose the left half cell of a galvanic cell apparatus is filled with a 3.00 M solution of M₂SO4 and the right half cell with a 30.0 mM solution of the same substance. Electrodes made of M are dipped into both solutions and a voltmeter is connected between them. The temperature of the apparatus is held constant at 35.0 °C. Which electrode will be positive? What voltage will the voltmeter show? Assume its positive lead is connected to the positive electrode. 0 Be sure your answer has a unit symbol, if necessary, and round it to 2 significant digits. left right x10 X Ś