Answered: Compound Heat of Vaporization (kJ/mol)…

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question

The table shown here lists the molar heats of vaporization
for several organic compounds. Use specific examples from
this list to illustrate how the heat of vaporization varies
with (a) molar mass, (b) molecular shape, (c) molecular
polarity, (d) hydrogen-bonding interactions. Explain these
comparisons in terms of the nature of the intermolecular
forces at work. (You may find it helpful to draw out the
structural formula for each compound.)

Compound
Heat of Vaporization (kJ/mol)
CH3CH2CH3
19.0
CH;CH,CH,CH,CH;
27.6
CH;CHB1CH3
31.8
CH;COCH3
32.0
CH3CH2CH,Br
33.6
CH;CH,CH2OH
47.3

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