The dctahedral compleX 1on [Mn(H20)6has moreunpaired spins than the octahedral complex ion[Mn(en)3]2. How many unpaired electrons arepresent in each species? Compare the Ao values forthese complexes.Complex ion# Unpaired electronsRelative A,|Mn(H,O)l**[Mn(en)3]2+CH2-CH2H2NNH2Ethylenediamineen

CFT explains the bonding interaction of central transition metal and ligand. This theory assumes…

Answered: Complex ion # Unpaired electrons…

Science

Chemistry

Complex ion # Unpaired electrons Relative A, [Mn(H,O),1²* [Mn(en)3]2*

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

See similar textbooks

Related questions

Q: [M(H2O)6]2- complex has 1 unpaired electron. What is M? V Cr Fe Mn Ti

A: IntroductionThe question states that the complex [M(H2O)6]2- possesses one unpaired electron. This…

Q: The following is a series of complex compounds whose central atom is a transition metal ion that has…

Q: K4 [Fe(CN)6] O кз [Fe(CN)6] [Ni(CO)4] O [Pt(NH3)4]Cl2 O ООО

Q: Q:Which of the following complications shows the deformity of Jan Teller? O [cr(OH2)6]3+ O…

A: A multiple choice question based on Jahn-Teller distortion, which is to be accomplished.

Q: What is the correct name for [Mn(CN)5]2-?

A: correct name for [Mn(CN)5]2- is :

Q: All of the following complexes will be colored EXCEPT O a. [Ni(H₂0)6] 2+ O b. [Fe(CN)6] 4- c.…

A: In coordination chemistry, central metal ion is bonded to ligand. Ligand donate electron density to…

Q: Chemistry Give the IUPAC name for the following metal complex: [Fe(H2O)4Cl2] The answer is not…

Q: An example of a coordination compound is [IrCIBr(en)2]Br. What is the oxidation state of the iridium…

Q: For each of the following pairs of complexes, identify the one that has the larger Crystal field…

Q: 1. Nickel forms two tetracyanido complexes, [Ni(CN)4]2 and [Ni(CN)4]4. Explain why cyanido complexes…

A: Nickel can form two tetracyanido complexes: Ni(CN)42- and Ni(CN)44-. The formation of cyanido…

Q: How many unpaired d electrons does ion [Fe(CN)6]3— have when it has a low spin electron…

Q: what is number of 3d electrons of the transition metal ion in [Ni(acac)2(OH2)2]

A: Transition metal complex [Ni(acac)2(OH)2]

Q: 1. What complex ion has the smallest octahedral field-splitting energy? Choices: o [Rh(OH₂)6]³+ o…

Q: Explain why the [Fe(CN)6]3- ion has one unpaired electron, while the [Fe(NCS)6]3- ion has five…

Q: How many unpaired electrons are in [Mn(NH3)6]3+

A: Given complex -ion is [Mn(NH3)6]+3 The metal ion is Mn+3 so Electronic configuration is Mn ⇒[As]…

Q: 3. Specify whether the following complexes hav (a) tetrahedral [Ni(CO)2(Cl)₂] 10 (b) [Pt(en)₂Cl₂]Cl₂…

A: Isomers are chemical compounds with which same chemical formula but different structural…

Q: How many (valence) d orbital electrons are present on each of the transition metal ions in the…

A: d orbital's electron count can be evaluated by knowing the correct oxidation state of central atom…

Q: isomers

Q: Predict the number of unpaired spins in: - [Cr(en)3 ] 2+ (ethylenediamine is a strong field ligand).…

A: Given, [Cr(en)3]2+ (ethylenediamine is a strong field ligand). And [Mn(H2O)6]2+ (water is a…

Q: What coordination isomer can be written for [Co(en)3][Cr(ox)3]?

A: Two coordination isomers are possible:- Answer [Co(en)3][Cr(ox)3] and [Cr(en)3][Co(ox)3] are the…

Q: For the complex Na3[Rh(NO2)3(CN)3], what is the number of unpaired electrons in the central metal…

Q: 1. What is the number of unpaired electrons per atom metal in this compound [Fe(en)2Cl2]Cl ?

A: ANSWER: Step 1: The [Fe(en2Cl2] Cl is a low-spin complex because of the bonding with strong-field…

Q: For the complex [Pd(NO)4]Br4, assume NO is a strong ligand, then which statement is true The complex…

A: According to the crystal field theory the ligand atom acts as point negative change and the metal…

Q: How do you name this? [Fe(NH3)6][Cr(CN)6]

A: Complex compound - [Fe(NH3)6][Cr(CN)6] We need to write the name of complex compound…

Q: hemistry is the most predominant complex [Ni(en)3 ]2+ , [Ni(OH2 )2(en)2 ]2+ , or [Ni(OH2 )4 (en)]2+…

Q: 1. The complexes ions of [Cu(H20)6]²+ and [Cu(NH3)4]2+ appear a pale shade of blue and a darker…

A: At the point when ligands append to a transition metal to shape a coordination complex, electrons in…

Q: Octahedral [Cr(en)3]3+ Octahedral [Cr(CI)6]6+ Square planar (Ti(en)2]2+ Tetrahedral [Nb(en)2]2+…

A: If the field is strong, it will have few unpaired electrons and thus low spin. If the field is weak,…

Q: Draw a crystal field splitting diagram for diamagnetic [Ni(CN):]².

Q: How many unpaired d-electrons are there in the complex ion, [Mn(CN)6]³°? 1 4 O OO O

A: Here, we need to find the number of unpaired electrons in the given complex. Mn is present as Mn3+…

Q: omplex ion? s

A: Chemical compounds that consist of an arrangement of neutral molecules or anions that are bound to a…

Q: Would you expect the complex [Cu(NH3)4(H2O)2]2+ to have isomers? If yes, what isomers would exist?

A: Yes there will be isomers of the complex [Cu(NH3)4(H2O)2]2+ this is because the H2O ligands can be…

Q: How many unpaired electrons are present for the Co ion in [Co(en)2(CN)2]CI? Enter your answer as a…

A: The charge on metal ions in any complex can be calculated by using the charge of the ligands and the…

Q: Assuming that all complexes contain the same metal cation and have the same shape, which…

A: The question concerns the relative stability of different coordination complexes, assuming they all…

Q: *Each of the following coordination compounds can take on cis- or trans- configurations. For each…

A: Complex (a) has octahedral geometry, in octahedral geometry same type of ligand having 90° angle…

Q: A coordination compound of ruthenium, [Ru(NH3)4Cl2]Cl, has shown some activity against leukemia in…

A: Generally in a coordination complex, a central metal atom (usually transition metal) is bonded to…

Q: Would you expect the complex [Cu(NH3)4(H2O)2]2+ to have isomers? If yes, what isomers would exist?

Q: [Co(NH3)63+] ion is diamagnetic but [Fe(H20)62+] is paramagnetic. Explain in handwritten

Q: The complex ion [Co(H₂O)]³+has a maximum absorbance wavelength of 600. nm. Calculate the…

A: For the given complex CFSE = -2.4∆o as it is d6 Low spin octahedral complex We know , 1 KJ/mol =…

Q: Which of the following fictitious compounds is more likely to be paramagnetic based off of your…

A: A coordination compound will be paramagnetic if the central transition metal or metal ion has at…

Q: Do the following complexes have geometric isomers? If none just say NO. a) tetrahedral…

Q: Fe4[Fe(CN)6]3 compound name

A: The given compound is Fe4[Fe(CN)6]3. To name this compound, we need to understand its structure and…

Q: Which complex ion is diamagnetic? [Mn(NH3)6]2+ [CoCl6]3− [Cr(H2O)4Cl2]+ [Co(NH3)6]3+

A: From the given complexes, which is diamagnetic has to be identified.

Q: Rank the following in order of decreasing and energy of light absorbed: [Cr(en)₃]³⁺, [Cr(CN)₆]³⁻,…

A: The splitting energy increases, as the strength of the ligand increases.

Q: Determine the d electron configuration of [Mn(H2O)6]3+complex.

A: The given complex is an octahedral complex and since H2O is a weak field ligand it can not cause…

Q: How many unpaired electrons do you predict for the tetrahedral [MnCl4]2- ion?

A: In the tetrahedral complexes, the three d orbitals (dxy, dyz, dxz) are higher in energy while the…

Concept explainers

Coordination Chemistry

It is a part of chemistry, in which the study of compounds that have central atoms surrounded by molecules or ions, known as ligand, is known as coordination chemistry.

Question

100%

The dctahedral compleX 1on [Mn(H20)6
has more
unpaired spins than the octahedral complex ion
[Mn(en)3]2. How many unpaired electrons are
present in each species? Compare the Ao values for
these complexes.
Complex ion
# Unpaired electrons
Relative A,
|Mn(H,O)l**
[Mn(en)3]2+
CH2-CH2
H2N
NH2
Ethylenediamine
en

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Step 3

VIEW

Step by step

Solved in 3 steps with 4 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Would you expect the complex [Co(en)3]Cl3 to have any unpaired electrons? Any isomers?
For which of the following octahedral complexes are isomers possible? Draw all the isomers. a) [Co(Cl)2(en)(NH3)2]+ b) [W(CO)4(py)2]
ENRICHMENT Fill in the blanks. Complete the statements about the features of the elements in the periodic table. Choose from the given pool of words below. CARD 1 #Fullfilled energy level atomic number orbital/sublevel family period f-block s-block p-block d-block electrons is one of the bases of how are the with Increasing elements in the Periodic Table are arranged. Elements similar properties are grouped as, 2 where the elements have the same number of electrons in their outermost shell and 1 3, where the elements have the same number of main energy levels. The periodic table of elements consists of 4 columns (Group 1A and Group 2A); the (Groups 3A to 8A); the, 2B); and the lanthanides and actinides. This number of columns for each 2 _, 6 columns 10 columns (Groups 3B to 14 columns under the group of 7 block corresponds to the number of electrons capable of filling up the s, p, dand forbitals. Given the electron configuration of the element oxygen, 1s2 s2$ 2p4, the numerical…
A complex with the following formula may possess which kind of isomerism? (Different letters A-F denote different ligands.) K[M(en)2A2]
For each of the following pairs of complexes, identify the one that has the larger Crystal Field Stabilization Energy. A) [Fe(CN)6]3- B) [Ru(CN)6]3-
5. Explain why [Fe(OH2)6]2+ is stable in aqueous solution but [Ti(OH2)6]4+ has never been isolated. 6. [Fe(OH₂)6]²+ is more readily oxidised in aqueous solution than [Fe(CN)6]. Briefly explain this observation.
In the lab, we found that [Co(en)3]3+ isomers are optically active. Would other [M(en)3]n+ complexes be optically active as well? Why or why not?
How many unpaired electrons does the manganese ion have in [Mn(CN) 6] 4–? 2 unpaired electrons 5 unpaired electrons 1 unpaired electron 3 unpaired electrons No unpaired electrons
Crystal field energy diagram for [Mn(CN)6]-3
Naming complex ions Name the following metal complexes or complex ions: formula [Mo(en)3]** [Au(OH), (CO),] 3+ [Cr(H₂O)₁]** name ☐ ☐ ☑ 5
Which of the following complex ions is Paramagnetic (has unpaired electrons)? Explain. a) weak field-[Cu(H₂O)(NH3)3(en)]* b) strong field-[Fe(SCN)(NH3)3(en)]²+
why does [Mn(terpy)2]2+ have an electron configuration of high spin d5 instead of low spin d5