Compare the Tolman electronic parameter of PMe3, PPh3, P(OET)3, and PCI3 using the table below. Which of these four phosphine groups has the greatest π-acidity? P(t-Bu)3 P(NMе2)3 PMe3 P(C6H4OMе)3 PPh3 P(C6H4F)3 P(OET) 3 PC13 PF3 (CO) /cm-¹ 2056.1 2061.9 2064.1 2066 2068.9 2071.3 2076.3 2097.0 2110.8 ~

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Compare the Tolman electronic parameter of PMe3, PPh3, P(OET)3, and PCI3 using the table
below. Which of these four phosphine groups has the greatest T-acidity?
P(t-Bu)3
P(NMе2)3
PMe3
P(C6H4OMе)3
PPh3
P(C6H4F)3
P(OET)3
PC13
PF3
(CO)/cm-1
2056.1
2061.9
2064.1
2066
2068.9
2071.3
2076.3
2097.0
2110.8
~
Transcribed Image Text:Compare the Tolman electronic parameter of PMe3, PPh3, P(OET)3, and PCI3 using the table below. Which of these four phosphine groups has the greatest T-acidity? P(t-Bu)3 P(NMе2)3 PMe3 P(C6H4OMе)3 PPh3 P(C6H4F)3 P(OET)3 PC13 PF3 (CO)/cm-1 2056.1 2061.9 2064.1 2066 2068.9 2071.3 2076.3 2097.0 2110.8 ~
O a. P(OET)3
O b. PPh 3
O c. PMe3
O d. PCl3
Transcribed Image Text:O a. P(OET)3 O b. PPh 3 O c. PMe3 O d. PCl3
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