CO(g) + Cl₂(g) → CoCl₂(g) The above reaction obeys the mechanism: Cl₂ 2CI Fast equilibrium Cl + CO = COCI Fast equilibrium COCI + Cl₂ , COCl₂ + Cl Slow X4 Cl2 2CI Fast Consider each of the following expressions and select "Yes" or "No" to indicate which represent a correct statement of the rate law that is consistent with the given mechanism. ✓d[COCl₂]/dt = K[Cl₂]³[co] ✓d[COCl₂]/dt = K[Cl₂]³/2[co] ✓-d[CO]/dt = K[CO][Cl₂]³/2 ✓-d[Cl₂]/dt = k[CI]² ✓d[COCl₂]/dt = K[CO][Cl₂] ✓d[COCl₂]/dt = K[CO][Cl₂]¹/²
CO(g) + Cl₂(g) → CoCl₂(g) The above reaction obeys the mechanism: Cl₂ 2CI Fast equilibrium Cl + CO = COCI Fast equilibrium COCI + Cl₂ , COCl₂ + Cl Slow X4 Cl2 2CI Fast Consider each of the following expressions and select "Yes" or "No" to indicate which represent a correct statement of the rate law that is consistent with the given mechanism. ✓d[COCl₂]/dt = K[Cl₂]³[co] ✓d[COCl₂]/dt = K[Cl₂]³/2[co] ✓-d[CO]/dt = K[CO][Cl₂]³/2 ✓-d[Cl₂]/dt = k[CI]² ✓d[COCl₂]/dt = K[CO][Cl₂] ✓d[COCl₂]/dt = K[CO][Cl₂]¹/²
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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CO(g) + Cl2(g) COCl2(g) |
The above reaction obeys the mechanism:
Cl2 2Cl Fast equilibrium
Cl + CO COCl Fast equilibrium COCl + Cl2 COCl2 + Cl Slow 2Cl Cl2 Fast |
Consider each of the following expressions and select "Yes" or "No" to indicate which represent a correct statement of the rate law that is consistent with the given mechanism.
d[COCl2]/dt = k[Cl2]3[CO]
d[COCl2]/dt = k[Cl2]3/2[CO]
-d[CO]/dt = k[CO][Cl2]3/2
-d[Cl2]/dt = k[Cl]2
d[COCl2]/dt = k[CO][Cl2]
d[COCl2]/dt = k[CO][Cl2]1/2
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