CO(g) + Cl₂(g) → CoCl₂(g) The above reaction obeys the mechanism: Cl₂ 2CI Fast equilibrium Cl + CO = COCI Fast equilibrium COCI + Cl₂ , COCl₂ + Cl Slow X4 Cl2 2CI Fast Consider each of the following expressions and select "Yes" or "No" to indicate which represent a correct statement of the rate law that is consistent with the given mechanism. ✓d[COCl₂]/dt = K[Cl₂]³[co] ✓d[COCl₂]/dt = K[Cl₂]³/2[co] ✓-d[CO]/dt = K[CO][Cl₂]³/2 ✓-d[Cl₂]/dt = k[CI]² ✓d[COCl₂]/dt = K[CO][Cl₂] ✓d[COCl₂]/dt = K[CO][Cl₂]¹/²

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
CO(g) + Cl2(g)  COCl2(g)

The above reaction obeys the mechanism:

Cl2  2Cl      Fast equilibrium

Cl + CO  COCl      Fast equilibrium

COCl + Cl2  COCl2 + Cl      Slow

2Cl  Cl2      Fast

Consider each of the following expressions and select "Yes" or "No" to indicate which represent a correct statement of the rate law that is consistent with the given mechanism.
    d[COCl2]/dt = k[Cl2]3[CO]
    d[COCl2]/dt = k[Cl2]3/2[CO]
    -d[CO]/dt = k[CO][Cl2]3/2
    -d[Cl2]/dt = k[Cl]2
    d[COCl2]/dt = k[CO][Cl2]
    d[COCl2]/dt = k[CO][Cl2]1/2

CO(g) + Cl₂(g) → CoCl₂(g)
The above reaction obeys the mechanism:
Cl₂
2Cl Fast equilibrium
Cl + CO
COCI Fast equilibrium
COCI + Cl₂ , COCl₂ + Cl
Slow
K4, Cl₂
2C1
Fast
Consider each of the following expressions and select "Yes" or "No" to indicate which represent a correct statement of the rate law that is consistent with the given mechanism.
✓d[COCl₂]/dt = K[Cl₂]³[co]
✓d[COCl₂]/dt = K[Cl₂]³/2[co]
✓-d[CO]/dt = K[CO][Cl₂]³/2
|-d[Cl₂]/dt = k[CI]²
✓d[CoCl₂]/dt = K[CO][Cl₂]
✓d[COCl₂]/dt = K[CO][Cl₂]¹/2
Transcribed Image Text:CO(g) + Cl₂(g) → CoCl₂(g) The above reaction obeys the mechanism: Cl₂ 2Cl Fast equilibrium Cl + CO COCI Fast equilibrium COCI + Cl₂ , COCl₂ + Cl Slow K4, Cl₂ 2C1 Fast Consider each of the following expressions and select "Yes" or "No" to indicate which represent a correct statement of the rate law that is consistent with the given mechanism. ✓d[COCl₂]/dt = K[Cl₂]³[co] ✓d[COCl₂]/dt = K[Cl₂]³/2[co] ✓-d[CO]/dt = K[CO][Cl₂]³/2 |-d[Cl₂]/dt = k[CI]² ✓d[CoCl₂]/dt = K[CO][Cl₂] ✓d[COCl₂]/dt = K[CO][Cl₂]¹/2
Expert Solution
steps

Step by step

Solved in 3 steps with 3 images

Blurred answer
Knowledge Booster
Rate Laws
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY