CO(g) + Cl₂(g) → CoCl₂(g) The above reaction obeys the mechanism: Cl₂ 2CI Fast equilibrium Cl + CO = COCI Fast equilibrium COCI + Cl₂ , COCl₂ + Cl Slow X4 Cl2 2CI Fast Consider each of the following expressions and select "Yes" or "No" to indicate which represent a correct statement of the rate law that is consistent with the given mechanism. ✓d[COCl₂]/dt = K[Cl₂]³[co] ✓d[COCl₂]/dt = K[Cl₂]³/2[co] ✓-d[CO]/dt = K[CO][Cl₂]³/2 ✓-d[Cl₂]/dt = k[CI]² ✓d[COCl₂]/dt = K[CO][Cl₂] ✓d[COCl₂]/dt = K[CO][Cl₂]¹/²

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Chapter1: Chemical Foundations
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CO(g) + Cl2(g)  COCl2(g)

The above reaction obeys the mechanism:

Cl2  2Cl      Fast equilibrium

Cl + CO  COCl      Fast equilibrium

COCl + Cl2  COCl2 + Cl      Slow

2Cl  Cl2      Fast

Consider each of the following expressions and select "Yes" or "No" to indicate which represent a correct statement of the rate law that is consistent with the given mechanism.
    d[COCl2]/dt = k[Cl2]3[CO]
    d[COCl2]/dt = k[Cl2]3/2[CO]
    -d[CO]/dt = k[CO][Cl2]3/2
    -d[Cl2]/dt = k[Cl]2
    d[COCl2]/dt = k[CO][Cl2]
    d[COCl2]/dt = k[CO][Cl2]1/2

CO(g) + Cl₂(g) → CoCl₂(g)
The above reaction obeys the mechanism:
Cl₂
2Cl Fast equilibrium
Cl + CO
COCI Fast equilibrium
COCI + Cl₂ , COCl₂ + Cl
Slow
K4, Cl₂
2C1
Fast
Consider each of the following expressions and select "Yes" or "No" to indicate which represent a correct statement of the rate law that is consistent with the given mechanism.
✓d[COCl₂]/dt = K[Cl₂]³[co]
✓d[COCl₂]/dt = K[Cl₂]³/2[co]
✓-d[CO]/dt = K[CO][Cl₂]³/2
|-d[Cl₂]/dt = k[CI]²
✓d[CoCl₂]/dt = K[CO][Cl₂]
✓d[COCl₂]/dt = K[CO][Cl₂]¹/2
Transcribed Image Text:CO(g) + Cl₂(g) → CoCl₂(g) The above reaction obeys the mechanism: Cl₂ 2Cl Fast equilibrium Cl + CO COCI Fast equilibrium COCI + Cl₂ , COCl₂ + Cl Slow K4, Cl₂ 2C1 Fast Consider each of the following expressions and select "Yes" or "No" to indicate which represent a correct statement of the rate law that is consistent with the given mechanism. ✓d[COCl₂]/dt = K[Cl₂]³[co] ✓d[COCl₂]/dt = K[Cl₂]³/2[co] ✓-d[CO]/dt = K[CO][Cl₂]³/2 |-d[Cl₂]/dt = k[CI]² ✓d[CoCl₂]/dt = K[CO][Cl₂] ✓d[COCl₂]/dt = K[CO][Cl₂]¹/2
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