Coal gasification produces an easily-transportable, clean-burning combination of carbon monoxide and hydrogen from coal by reacting it with steam, like this: C(s) + H₂O(g) → CO(g) + H₂(g) Suppose an engineer decides to study the rate of this reaction. He prepares four reaction vessels with 95.3 g of solid carbon and 13.5 g of steam each. The volume and temperature of each vessel is shown in the table below. Arrange the reaction vessels in decreasing order of initial rate of reaction. In other words, select a "1" next to the vessel in which the engineer can reasonably expect the initial rate of reaction to be highest, a "2" next to the vessel in which the initial rate of reaction would be next highest, and so on. vessel volume temperature A B C D 5.0 L 5.0 L 5.0 L 5.0 L 360. °C 370. °C 390. °C 340. °C initial rate of reaction ? ? ? ? ✓
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
![Coal gasification produces an easily-transportable, clean-burning combination of carbon monoxide and hydrogen from coal by reacting it with steam, like this:
C(s) + H₂O(g) → CO(g) + H₂(g)
- -
Suppose an engineer decides to study the rate of this reaction. He prepares four reaction vessels with 95.3 g of solid carbon and 13.5 g of steam each. The
volume and temperature of each vessel is shown in the table below.
Arrange the reaction vessels in decreasing order of initial rate of reaction. In other words, select a "1" next to the vessel in which the engineer can reasonably
expect the initial rate of reaction to be highest, a "2" next to the vessel in which the initial rate of reaction would be next highest, and so on.
vessel volume temperature
A
B
C
D
5.0 L
5.0 L
5.0 L
5.0 L
360. °C
370. °C
390. °C
340. °C
X
initial rate of
reaction
?
?
?
?
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