Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Can you check My work and tell me if these are right regarding if they are R rotating or S rotations, please? Thank you.
![**Title: Understanding Stereochemistry: R & S Configurations**
This educational page aims to explain the R (Rectus) and S (Sinister) configurations in stereochemistry with examples.
---
**1. Example a):**
- Structure: Amine group (\(NH_2\))
- Configuration: R
**2. Example b):**
- Structure: Benzene derivative with Bromine (Br)
- Configuration: S
**3. Example c):**
- Structure: Chlorine (Cl) attached, numbered 1 to 4
- Configuration: S
**4. Example d):**
- Structure: Cyclohexane chair conformation with Chlorine (Cl)
- Configuration: S
**5. Example e):**
- Structure: Furan derivative
- Configuration: R
**6. Example f):**
- Structure: Cyclohexanol with adjacent substituents
- Configuration: S
**7. Example g):**
- Structure: Chemical with acetal group
- Configuration: S
**8. Example h):**
- Structure: Nitrile group (\(CN\)) attached
- Configuration: S
**9. Example i):**
- Structure: A complex bicyclic compound
- Configuration: R
**10. Example j):**
- Structure: A ketone within a ring structure
- Configuration: R
---
**Additional Notes:**
- *Clockwise is R, Counter-clockwise is S*: It has been annotated that when the priorities decrease in a clockwise manner, the configuration is R. Conversely, a counter-clockwise decrease indicates an S configuration.
Through these examples, students can comprehend how to denote the R and S configurations by considering the spatial arrangement of atoms or groups around a chiral center, following Cahn-Ingold-Prelog priority rules.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F63e2e494-b56f-474b-94e6-a1b0d865891f%2F7ebbe220-b51d-4b32-8d63-e6394225a865%2Fjtab6q8_processed.jpeg&w=3840&q=75)
Transcribed Image Text:**Title: Understanding Stereochemistry: R & S Configurations**
This educational page aims to explain the R (Rectus) and S (Sinister) configurations in stereochemistry with examples.
---
**1. Example a):**
- Structure: Amine group (\(NH_2\))
- Configuration: R
**2. Example b):**
- Structure: Benzene derivative with Bromine (Br)
- Configuration: S
**3. Example c):**
- Structure: Chlorine (Cl) attached, numbered 1 to 4
- Configuration: S
**4. Example d):**
- Structure: Cyclohexane chair conformation with Chlorine (Cl)
- Configuration: S
**5. Example e):**
- Structure: Furan derivative
- Configuration: R
**6. Example f):**
- Structure: Cyclohexanol with adjacent substituents
- Configuration: S
**7. Example g):**
- Structure: Chemical with acetal group
- Configuration: S
**8. Example h):**
- Structure: Nitrile group (\(CN\)) attached
- Configuration: S
**9. Example i):**
- Structure: A complex bicyclic compound
- Configuration: R
**10. Example j):**
- Structure: A ketone within a ring structure
- Configuration: R
---
**Additional Notes:**
- *Clockwise is R, Counter-clockwise is S*: It has been annotated that when the priorities decrease in a clockwise manner, the configuration is R. Conversely, a counter-clockwise decrease indicates an S configuration.
Through these examples, students can comprehend how to denote the R and S configurations by considering the spatial arrangement of atoms or groups around a chiral center, following Cahn-Ingold-Prelog priority rules.
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