Clearly label all atomic and molecular orbitals and put the correct number of electrons into the molecular orbitals. Provide correct LGO reducible representation for ligand group orbitals. 1.Consider the transition metal complex [NiC14]2- (square planar geometry). 1a. Construct a plausible Molecular Orbital (MO) energy diagram for [NiCl4]2-. Consider \ sigma - bonding only and disregard Cl s-orbitals. Calculate total number of electrons and predict whether [NiCl4]2- is diamagnetic or paramagnetic. 1b. Determine the symmetry irreducible representations for p-orbitals of chlorine which may participate in -bonding (two extra p-orbitals per Cl which are perpendicular to Ni-Cl bond). Which of those orbitals will remain non-bonding?

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Chapter21: Transition Metals And Coordination Chemistry
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Clearly label all atomic and molecular orbitals and put the correct number of electrons into
the molecular orbitals. Provide correct LGO reducible representation for ligand group
orbitals.
1.Consider the transition metal complex [NiC14]2- (square planar geometry).
1a. Construct a plausible Molecular Orbital (MO) energy diagram for [NiCl4]2-. Consider \
sigma -
bonding only and disregard Cl s-orbitals. Calculate total number of electrons and predict
whether [NiCl4]2- is diamagnetic or paramagnetic.
1b. Determine the symmetry irreducible representations for p-orbitals of chlorine which may
participate in -bonding (two extra p-orbitals per Cl which are perpendicular to Ni-Cl bond).
Which of those orbitals will remain non-bonding?
Transcribed Image Text:Clearly label all atomic and molecular orbitals and put the correct number of electrons into the molecular orbitals. Provide correct LGO reducible representation for ligand group orbitals. 1.Consider the transition metal complex [NiC14]2- (square planar geometry). 1a. Construct a plausible Molecular Orbital (MO) energy diagram for [NiCl4]2-. Consider \ sigma - bonding only and disregard Cl s-orbitals. Calculate total number of electrons and predict whether [NiCl4]2- is diamagnetic or paramagnetic. 1b. Determine the symmetry irreducible representations for p-orbitals of chlorine which may participate in -bonding (two extra p-orbitals per Cl which are perpendicular to Ni-Cl bond). Which of those orbitals will remain non-bonding?
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