Classify the following substituents according to whether they are electron donors or electron acceptors relative to hydrogen by the resonance and the inductive mechanisms. a = acceptor d = donor n = no effect 1. 2. 3. :0: Ö: 0: methanesulfonyl -CH3 :0: -OCH₂CH3 OCH₂CH3 Inductive effect Inductive effect —C—CH,CH,CH,N(CH3)2 Resonance effect Resonance effect Inductive effect Resonance effect

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Classify the following substituents according to whether they are electron donors or electron acceptors relative to hydrogen by the resonance and the inductive mechanisms.
a = acceptor
d = donor
n = no effect
1.
-S-CH3
3.
methanesulfonyl
:0:
2. -P-OCH₂CH3 Inductive effect
OCH₂CH3
Inductive effect
:0:
C—CH,CH,CH,N(CH3)2
. Resonance effect
Resonance effect
Inductive effect
Resonance effect
Transcribed Image Text:Classify the following substituents according to whether they are electron donors or electron acceptors relative to hydrogen by the resonance and the inductive mechanisms. a = acceptor d = donor n = no effect 1. -S-CH3 3. methanesulfonyl :0: 2. -P-OCH₂CH3 Inductive effect OCH₂CH3 Inductive effect :0: C—CH,CH,CH,N(CH3)2 . Resonance effect Resonance effect Inductive effect Resonance effect
The following reaction scheme shows the conditions for the formation of dinitro methyl benzoate, compound B, via compound A.
ob
CH3
O
HNO3, H₂SO4
a Draw the structure of compound A.
A
HNO3, H₂SO4
B
• Remember to include all of the formal charges on the atoms of any nitro groups.
Transcribed Image Text:The following reaction scheme shows the conditions for the formation of dinitro methyl benzoate, compound B, via compound A. ob CH3 O HNO3, H₂SO4 a Draw the structure of compound A. A HNO3, H₂SO4 B • Remember to include all of the formal charges on the atoms of any nitro groups.
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