Classify the following substituents according to whether they are electron donors or electron acceptors relative to hydrogen by the resonance and the inductive mechanisms. a = acceptor d = donor n = no effect 1. 2. 3. :0: Ö: 0: methanesulfonyl -CH3 :0: -OCH₂CH3 OCH₂CH3 Inductive effect Inductive effect —C—CH,CH,CH,N(CH3)2 Resonance effect Resonance effect Inductive effect Resonance effect
Classify the following substituents according to whether they are electron donors or electron acceptors relative to hydrogen by the resonance and the inductive mechanisms. a = acceptor d = donor n = no effect 1. 2. 3. :0: Ö: 0: methanesulfonyl -CH3 :0: -OCH₂CH3 OCH₂CH3 Inductive effect Inductive effect —C—CH,CH,CH,N(CH3)2 Resonance effect Resonance effect Inductive effect Resonance effect
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![Classify the following substituents according to whether they are electron donors or electron acceptors relative to hydrogen by the resonance and the inductive mechanisms.
a = acceptor
d = donor
n = no effect
1.
-S-CH3
3.
methanesulfonyl
:0:
2. -P-OCH₂CH3 Inductive effect
OCH₂CH3
Inductive effect
:0:
C—CH,CH,CH,N(CH3)2
. Resonance effect
Resonance effect
Inductive effect
Resonance effect](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F0956b951-904a-4e8f-b73a-a0aa05e6cd9c%2Fe4ae109c-b9c0-4762-b43e-688652d18271%2Fdap7xuv_processed.png&w=3840&q=75)
Transcribed Image Text:Classify the following substituents according to whether they are electron donors or electron acceptors relative to hydrogen by the resonance and the inductive mechanisms.
a = acceptor
d = donor
n = no effect
1.
-S-CH3
3.
methanesulfonyl
:0:
2. -P-OCH₂CH3 Inductive effect
OCH₂CH3
Inductive effect
:0:
C—CH,CH,CH,N(CH3)2
. Resonance effect
Resonance effect
Inductive effect
Resonance effect
![The following reaction scheme shows the conditions for the formation of dinitro methyl benzoate, compound B, via compound A.
ob
CH3
O
HNO3, H₂SO4
a Draw the structure of compound A.
A
HNO3, H₂SO4
B
• Remember to include all of the formal charges on the atoms of any nitro groups.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F0956b951-904a-4e8f-b73a-a0aa05e6cd9c%2Fe4ae109c-b9c0-4762-b43e-688652d18271%2F17ilyu_processed.png&w=3840&q=75)
Transcribed Image Text:The following reaction scheme shows the conditions for the formation of dinitro methyl benzoate, compound B, via compound A.
ob
CH3
O
HNO3, H₂SO4
a Draw the structure of compound A.
A
HNO3, H₂SO4
B
• Remember to include all of the formal charges on the atoms of any nitro groups.
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