Answered: Cl2 (g) + CO (g) <-> COCl2 (g) Delta…

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Cl₂ (g) + CO (g) <-> COCl₂ (g) Delta H_rxn = -109 kj/mol_rxn

1. At equilibrium, the container holds the most molecules of which gas, Cl₂(g) of COCl₂(g)? Explain you answer.

2. A student hypothesizes that if the temperature of the container is decreased after time t₉, the mole fraction of Cl₂ in the container will increase. Do you agree or disagree with the student's hypothesis? Justify your answer.

3. Which gas, Cl₂(g) or COCl₂(g), will deviate most from the ideal gas law at low temperature? Justify your answer.

Pco
Peocla
Time
(atm)
(atm)
(atm)
to
1.0
1.0
0.0
0.78
0.78
0.22
t2
0.62
0.62
0.38
t3
0.51
0.51
0.49
t4
0.45
0.45
0.55
to
0.42
0.42
0.58
to
0.41
0.41
0.59
t7
0.40
0.40
0.60
ts
0.40
0.40
0.60
tg
0.40
0.40
0.60

Definition Definition Any of various laws that describe the ways in which volume, temperature, pressure, and other conditions correlate when matter is in a gaseous state. At a constant temperature, the pressure of a particular amount of gas is inversely proportional with its volume (Boyle's Law) In a closed system with constant pressure, the volume of an ideal gas is in direct relation with its temperature (Charles's Law) At a constant volume, the pressure of a gas is in direct relation to its temperature (Gay-Lussac's Law) If the volume of all gases are equal and under the a similar temperature and pressure, then they contain an equal number of molecules (Avogadro's Law) The state of a particular amount of gas can be determined by its pressure, volume and temperature (Ideal Gas law)

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