Citric acid is triprotic (H3Cit), with acidity constants pKa 1 = 3.13, pKa2 = 4.76, and pKa3 = 6.40. (a) Write out the expressions for 0, 1, 2, and 3 as a function of the Ka values and()H+. (b) Identify the region where each citrate species is dominant. (c) Draw a log C - pH diagram for a solution with 101 M TOTCit over the pH range1.0

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Citric acid is triprotic (H3Cit), with acidity constants pKa
1 = 3.13, pKa2 = 4.76, and pKa3
=
6.40. (a) Write
out the expressions for 0, 1, 2, and 3 as a function of
the Ka values and()H+. (b) Identify the region where
each citrate species is dominant. (c) Draw a log C - pH
diagram for a solution with 101 M TOTCit over the pH
range1.0
Transcribed Image Text:Citric acid is triprotic (H3Cit), with acidity constants pKa 1 = 3.13, pKa2 = 4.76, and pKa3 = 6.40. (a) Write out the expressions for 0, 1, 2, and 3 as a function of the Ka values and()H+. (b) Identify the region where each citrate species is dominant. (c) Draw a log C - pH diagram for a solution with 101 M TOTCit over the pH range1.0
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