CI 1780 cm¹ CH3 H 1730 cm¹ 1715 cm ¹ lo 1710 cm¹ 요 NH₂ 1650 cm³¹ io 1580 cm 1 • Provide the next-best resonance structure for four of the structures above. • Pick any two and state how the resonance structures can be used to help correlate structures with the given values for stretching frequencies.

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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The carbonyl functional group C=0 tends to show up around 1700 cm. In truth, there
is some variability in exactly where the C=0 stretch appears. Data is given below.
Some are at larger values, consistent with shorter bonds. Some are at smaller
values, consistent with longer bonds.
O
1780 cm ¹
O
H
CH3
1730 cm 1 1715 cm 1
1710 cm 1
O
NH₂
1650 cm 1
1580 cm 1
• Provide the next-best resonance structure for four of the structures above.
• Pick any two and state how the resonance structures can be used to help
correlate structures with the given values for stretching frequencies.
Transcribed Image Text:The carbonyl functional group C=0 tends to show up around 1700 cm. In truth, there is some variability in exactly where the C=0 stretch appears. Data is given below. Some are at larger values, consistent with shorter bonds. Some are at smaller values, consistent with longer bonds. O 1780 cm ¹ O H CH3 1730 cm 1 1715 cm 1 1710 cm 1 O NH₂ 1650 cm 1 1580 cm 1 • Provide the next-best resonance structure for four of the structures above. • Pick any two and state how the resonance structures can be used to help correlate structures with the given values for stretching frequencies.
Expert Solution
Step 1

Correlate the carbonyl frequency with their respective structures.how does bond length deviate  the mean value of carbonyl streching frequency. Answer these two questions based upon these two concepts.

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