Choose the molecule/ion that is expected to exhibit non-ideal bond angles. 3- NO3 XeF4 XeF2 Xe03

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Chapter1: Chemical Foundations
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**Question:**

Choose the molecule/ion that is expected to exhibit non-ideal bond angles.

**Options:**

- ○ \( \text{PO}_4^{3-} \)
- ○ \( \text{NO}_3^{-} \)
- ○ \( \text{XeF}_4 \)
- ○ \( \text{XeF}_2 \)
- ○ \( \text{XeO}_3 \)

**Explanation:**

This question requires you to identify which molecule or ion among the given options is likely to have bond angles that deviate from the ideal geometric angles. Generally, the ideal bond angles depend on the molecular geometry:

- **Tetrahedral (e.g., \( \text{PO}_4^{3-} \))**: Ideal angle is 109.5°.
- **Trigonal planar (e.g., \( \text{NO}_3^{-} \))**: Ideal angle is 120°.
- **Square planar (e.g., \( \text{XeF}_4 \))**: Ideal angle is 90°.
- **Linear (e.g., \( \text{XeF}_2 \))**: Ideal angle is 180°.
- **Trigonal pyramidal (e.g., \( \text{XeO}_3 \))**: Often have non-ideal angles due to lone pair-bond pair repulsion.

**Hint:**
Consider the presence of lone pairs and their effect on bond angles, as this will lead to non-ideal bond angles in certain molecular geometries.
Transcribed Image Text:**Question:** Choose the molecule/ion that is expected to exhibit non-ideal bond angles. **Options:** - ○ \( \text{PO}_4^{3-} \) - ○ \( \text{NO}_3^{-} \) - ○ \( \text{XeF}_4 \) - ○ \( \text{XeF}_2 \) - ○ \( \text{XeO}_3 \) **Explanation:** This question requires you to identify which molecule or ion among the given options is likely to have bond angles that deviate from the ideal geometric angles. Generally, the ideal bond angles depend on the molecular geometry: - **Tetrahedral (e.g., \( \text{PO}_4^{3-} \))**: Ideal angle is 109.5°. - **Trigonal planar (e.g., \( \text{NO}_3^{-} \))**: Ideal angle is 120°. - **Square planar (e.g., \( \text{XeF}_4 \))**: Ideal angle is 90°. - **Linear (e.g., \( \text{XeF}_2 \))**: Ideal angle is 180°. - **Trigonal pyramidal (e.g., \( \text{XeO}_3 \))**: Often have non-ideal angles due to lone pair-bond pair repulsion. **Hint:** Consider the presence of lone pairs and their effect on bond angles, as this will lead to non-ideal bond angles in certain molecular geometries.
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