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CHM 2 125 LABORAT ORY MANUAL 4. Draw the structures of the product of the reaction of each of the organometallics below with acetophenone (CH;C(O)C,Hs). a. butyllithium b. phenylmagnesium bromide c. lithium dicyclohexylcuprate(1) 5. Draw the structures of the product of the reaction of an excess of each of the organometallics below with benzoic acid (C,H5COOH) (you may need to look up the reaction in the chapter on carboxylic acids). a. butyllithium b. phenylmagnesium bromide c. lithium dicyclohexylcuprate(I) 6. In the MS spectrum of the product of this experiments (benzaldehyde + allylzinc bromide) identify the fragments at m/e = 148, 130, 107. %3D 7. The reaction of allyllithium with the aldehyde shown gives the indicated product. Show how the observed product was formed (mechanism). CO2CH3 1. Allyllithium 2. H', Н,О CНО

CHM 2 125 LABORAT ORY MANUAL 4. Draw the structures of the product of the reaction of each of the organometallics below with acetophenone (CH;C(O)C,Hs). a. butyllithium b. phenylmagnesium bromide c. lithium dicyclohexylcuprate(1) 5. Draw the structures of the product of the reaction of an excess of each of the organometallics below with benzoic acid (C,H5COOH) (you may need to look up the reaction in the chapter on carboxylic acids). a. butyllithium b. phenylmagnesium bromide c. lithium dicyclohexylcuprate(I) 6. In the MS spectrum of the product of this experiments (benzaldehyde + allylzinc bromide) identify the fragments at m/e = 148, 130, 107. %3D 7. The reaction of allyllithium with the aldehyde shown gives the indicated product. Show how the observed product was formed (mechanism). CO2CH3 1. Allyllithium 2. H', Н,О CНО

Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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CHM 2 125 LABORAT ORY MANUAL 4. Draw the structures of the product of the reaction of each of the organometallics below with acetophenone (CH;C(O)C,Hs). a. butyllithium b. phenylmagnesium bromide c. lithium dicyclohexylcuprate(1) 5. Draw the structures of the product of the reaction of an excess of each of the organometallics below with benzoic acid (C,H5COOH) (you may need to look up the reaction in the chapter on carboxylic acids). a. butyllithium b. phenylmagnesium bromide c. lithium dicyclohexylcuprate(I) 6. In the MS spectrum of the product of this experiments (benzaldehyde + allylzinc bromide) identify the fragments at m/e = 148, 130, 107. %3D 7. The reaction of allyllithium with the aldehyde shown gives the indicated product. Show how the observed product was formed (mechanism). CO2CH3 1. Allyllithium 2. H', Н,О CНО
Transcribed Image Text:CHM 2 125 LABORAT ORY MANUAL 4. Draw the structures of the product of the reaction of each of the organometallics below with acetophenone (CH;C(O)C,Hs). a. butyllithium b. phenylmagnesium bromide c. lithium dicyclohexylcuprate(1) 5. Draw the structures of the product of the reaction of an excess of each of the organometallics below with benzoic acid (C,H5COOH) (you may need to look up the reaction in the chapter on carboxylic acids). a. butyllithium b. phenylmagnesium bromide c. lithium dicyclohexylcuprate(I) 6. In the MS spectrum of the product of this experiments (benzaldehyde + allylzinc bromide) identify the fragments at m/e = 148, 130, 107. %3D 7. The reaction of allyllithium with the aldehyde shown gives the indicated product. Show how the observed product was formed (mechanism). CO2CH3 1. Allyllithium 2. H', Н,О CНО
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