The reaction 2NO(g) + Cl₂ (g) → 2NOC1(g) was studied at -10°C. The following results were obtained where A[C1₂] At [C1z]o Rate = [NO]o (mol/L) (mol/L) (mol/L.min) 0.12 0.12 0.31 0.12 0.24 0.62 0.24 0.24 2.49 Initial Rate a What is the rate law? (Use k for the rate constant. ) Rate = a The reaction of NO₂ (g) and CO(g) is thought to occur in two steps: Step 1 Slow NO₂(g) + NO2(g) → NO(g) + NO3 (9) Step 2 Fast NO3(g) + CO(g) → NO2 (g) + CO₂(g) Add the elementary steps to give the overall, stoichiometric reaction. (Use the lowest possible coefficients. Be sure to specify states such as (aq) or (s). If a box is not needed, leave it blank.) +

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The reaction
2NO(g) + Cl₂ (g) → 2NOC1(g)
was studied at -10°C. The following results were obtained where
A[C1₂]
At
[C1z]o
Rate =
[NO]o
(mol/L) (mol/L) (mol/L.min)
0.12
0.12
0.31
0.12
0.24
0.62
0.24
0.24
2.49
Initial Rate
a What is the rate law?
(Use k for the rate constant. )
Rate =
Transcribed Image Text:The reaction 2NO(g) + Cl₂ (g) → 2NOC1(g) was studied at -10°C. The following results were obtained where A[C1₂] At [C1z]o Rate = [NO]o (mol/L) (mol/L) (mol/L.min) 0.12 0.12 0.31 0.12 0.24 0.62 0.24 0.24 2.49 Initial Rate a What is the rate law? (Use k for the rate constant. ) Rate =
a The reaction of
NO₂ (g) and
CO(g) is thought to occur in two steps:
Step 1 Slow
NO₂(g) + NO2(g) → NO(g) + NO3 (9)
Step 2 Fast
NO3(g) + CO(g) → NO2 (g) + CO₂(g)
Add the elementary steps to give the overall, stoichiometric reaction.
(Use the lowest possible coefficients. Be sure to specify states such as (aq) or (s). If a box is not needed, leave it blank.)
+
Transcribed Image Text:a The reaction of NO₂ (g) and CO(g) is thought to occur in two steps: Step 1 Slow NO₂(g) + NO2(g) → NO(g) + NO3 (9) Step 2 Fast NO3(g) + CO(g) → NO2 (g) + CO₂(g) Add the elementary steps to give the overall, stoichiometric reaction. (Use the lowest possible coefficients. Be sure to specify states such as (aq) or (s). If a box is not needed, leave it blank.) +
Expert Solution
Step 1: Determine the rate law of the reaction and overall reaction:

Given,

(i) The reaction:

NO(g) + Cl2 (g) rightwards arrow 2 NOCl (g)  at -10 oC

Rate = negative space fraction numerator increment open square brackets C l subscript 2 close square brackets over denominator increment t end fraction

The rate law of the reaction :  Rate = k [ NO ]m[ Cl2 ]n

(ii)   The elementary reaction steps of NO2 (g) and  CO (g):

S t e p 1 space left parenthesis s l o w right parenthesis space colon space space space N O subscript 2 left parenthesis g right parenthesis end subscript space plus space N O subscript left parenthesis g right parenthesis end subscript space rightwards arrow space N O subscript left parenthesis g right parenthesis end subscript space plus space N O subscript 3 space left parenthesis g right parenthesis end subscript space

S t e p space 2 space left parenthesis space F a s t space right parenthesis space colon space space N O subscript 3 subscript space left parenthesis g right parenthesis end subscript space plus space C O subscript left parenthesis g right parenthesis end subscript space rightwards arrow space N O subscript 2 space left parenthesis g right parenthesis end subscript space plus space C O subscript 2 space left parenthesis g right parenthesis end subscript space space


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