Chemistry Question

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Step 1

If two compounds have similar or comparable molecular mass then on the basis of Intermolecular interactions, we can compare te boiling point of compounds.

since the boiling point is inversely proportional to vapor pressure, therefore we can also compare their vapor pressure.

 

Step 2

molar mass of HF (compound B)= 20 g/mol

molar mass of hydrocarbon (compound A) = 30 g/mol

 

The molar masses of given compounds are nearly similar (difference of 10-15 g is OKAY !) 

 

Step 3

Order of strength of Intermolecular interactions:

                                                      H-bonding >dipole-dipole>london dispersions

The more the strength of intermolecular forces between the molecules, the higher will the boiling and melting point (because more energy is required to take them away from each other). 

  • Dipole-Dipole interactions are present in polar molecular.
  • H-bonding is present between the highly electronegative atom (F, O, Cl) and the H-atoms attached with highly electronegative atoms (F, O, N).

 

 

 

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