**Title: Using Infrared Spectroscopy to Distinguish Between Constitutional Isomers** **Introduction:** Infrared spectroscopy is a powerful tool used in chemistry to differentiate between constitutional isomers. These isomers share the same molecular formula but differ in the connectivity of their atoms. **Comparison of Isomeric Pairs:** **(a) Isomeric Pair:** 1. CH₃C≡CCH₃ 2. CH₃CH₂C≡CH **(b) Isomeric Pair:** 1. CH₃CCH=CHCH₃ (with a carbonyl group indicated as C=O) 2. CH₃CCH₂CH=CH₂ (with a carbonyl group indicated as C=O) **(c) Isomeric Pair:** 1. H₂C=CHOCH₃ 2. CH₃CH₂CHO **Analysis Method:** To distinguish between these isomers using infrared spectroscopy, focus on the functional groups present in each compound. Key IR absorption bands to look for include: - The C≡C stretch in alkynes - The C=O stretch in carbonyl compounds - The C=C stretch in alkenes By analyzing these characteristic peaks, one can identify the presence of different functional groups and thus distinguish between isomers effectively.

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**Title: Using Infrared Spectroscopy to Distinguish Between Constitutional Isomers**

**Introduction:**
Infrared spectroscopy is a powerful tool used in chemistry to differentiate between constitutional isomers. These isomers share the same molecular formula but differ in the connectivity of their atoms.

**Comparison of Isomeric Pairs:**

**(a) Isomeric Pair:**
1. CH₃C≡CCH₃
2. CH₃CH₂C≡CH

**(b) Isomeric Pair:**
1. CH₃CCH=CHCH₃ (with a carbonyl group indicated as C=O)
2. CH₃CCH₂CH=CH₂ (with a carbonyl group indicated as C=O)

**(c) Isomeric Pair:**
1. H₂C=CHOCH₃
2. CH₃CH₂CHO

**Analysis Method:**
To distinguish between these isomers using infrared spectroscopy, focus on the functional groups present in each compound. Key IR absorption bands to look for include:
- The C≡C stretch in alkynes
- The C=O stretch in carbonyl compounds
- The C=C stretch in alkenes

By analyzing these characteristic peaks, one can identify the presence of different functional groups and thus distinguish between isomers effectively.
Transcribed Image Text:**Title: Using Infrared Spectroscopy to Distinguish Between Constitutional Isomers** **Introduction:** Infrared spectroscopy is a powerful tool used in chemistry to differentiate between constitutional isomers. These isomers share the same molecular formula but differ in the connectivity of their atoms. **Comparison of Isomeric Pairs:** **(a) Isomeric Pair:** 1. CH₃C≡CCH₃ 2. CH₃CH₂C≡CH **(b) Isomeric Pair:** 1. CH₃CCH=CHCH₃ (with a carbonyl group indicated as C=O) 2. CH₃CCH₂CH=CH₂ (with a carbonyl group indicated as C=O) **(c) Isomeric Pair:** 1. H₂C=CHOCH₃ 2. CH₃CH₂CHO **Analysis Method:** To distinguish between these isomers using infrared spectroscopy, focus on the functional groups present in each compound. Key IR absorption bands to look for include: - The C≡C stretch in alkynes - The C=O stretch in carbonyl compounds - The C=C stretch in alkenes By analyzing these characteristic peaks, one can identify the presence of different functional groups and thus distinguish between isomers effectively.
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