Chemistry 2a. Give the division of the d-orbitals in an octahedron and name the orbitals. Give the possession of Fe²+ ion: draw two possible situations. 2b. Calculate the crystal field stabilization energy for both with the correct unit. 2c. Give the three equilibrium equations and the equation for the stability constant K3 for the reaction of a solution of FeCl₂ with 2,2'-bipyridine (see the figure); N- 2d. The stability constants of the formation of 2,2-bipyridine complex with Fe 2+ in water are; logk₁ = 4.2; logk₂= 3.7; logK;-9.3. K3 deviates from the normal trend. What will be the value of the normal trend? Give the possible reason for the deviating value of K3.
Chemistry 2a. Give the division of the d-orbitals in an octahedron and name the orbitals. Give the possession of Fe²+ ion: draw two possible situations. 2b. Calculate the crystal field stabilization energy for both with the correct unit. 2c. Give the three equilibrium equations and the equation for the stability constant K3 for the reaction of a solution of FeCl₂ with 2,2'-bipyridine (see the figure); N- 2d. The stability constants of the formation of 2,2-bipyridine complex with Fe 2+ in water are; logk₁ = 4.2; logk₂= 3.7; logK;-9.3. K3 deviates from the normal trend. What will be the value of the normal trend? Give the possible reason for the deviating value of K3.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Atomic Structure
The basic structure of an atom is defined as the component-level of atomic structure of an atom. Precisely speaking an atom consists of three major subatomic particles which are protons, neutrons, and electrons. Many theories have been stated for explaining the structure of an atom.
Shape of the D Orbital
Shapes of orbitals are an approximate representation of boundaries in space for finding electrons occupied in that respective orbital. D orbitals are known to have a clover leaf shape or dumbbell inside where electrons can be found.
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