Chem 129 Topic Set 7 Variations of titration and Buffers G. How would you make 350mL of a buffer with a total concentration of 0.75M and a pH of 9.00 from the list of materials below? (your answer should include the volumes of two solutions and the amount of DI water needed to reach the total volume) [remember: vol* total conc->total moles->moles weak, targetpH->ratio->stoich->moles strong] i. A solution of 1.25 M hydrochloric acid ii. A solution of 1.25 M sodium hydroxide iii. A solution of 1.25 M chloroacetic acid (pKa = 2.85) iv. A solution of 1.25 M ammonia (pka = 9.25) v. A solution of 1.25 M carbonic acid (pKa1 = 6.37, pKa2 = 10.32 vi. A solution of 1.25 M acetic acid (pka = 4.75) Dilutionen 1) What would be the volume of weak component and what would be the volume of strong component? MV MV (0.75) (350) = 1.25 (x) Polypraticac x = 210 mL 2) What would be the capacity of the buffer? idic behavig 3) After the buffer is made, what would the pH change to if 24.5mL of 1.25 M hydrochloric acid is added?

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G. How would you make 350mL of a buffer with a total concentration of 0.75M and a pH of 9.00
from the list of materials below? (your answer should include the volumes of two solutions and
the amount of DI water needed to reach the total volume)
[remember: vol* total conc->total moles->moles weak,
targetpH->ratio->stoich->moles strong]
i. A solution of 1.25 M hydrochloric acid
ii. A solution of 1.25 M sodium hydroxide
iii. A solution of 1.25 M chloroacetic acid (pKa = 2.85)
iv. A solution of 1.25 M ammonia (pka = 9.25)
v. A solution of 1.25 M carbonic acid (pKa1 = 6.37, pka2 = 10.32
vi. A solution of 1.25 M acetic acid (pka = 4.75)
Dilution 1) What would be the volume of weak component and what would be the volume of
strong component?
Polyprati
Chem 129 Topic Set 7
Variations of titration and Buffers
Weak
MV MV
(0.75) (850) = 1.25 (x)
pk 2) What would be the capacity of the buffer?
behavior
x = 210 mL
3) After the buffer is made, what would the pH change to if 24.5mL of 1.25 M hydrochloric
acid is added?
4) After the buffer is made, what would pH
to
IF 37.3 mL of 1.25 M sodium
was added
change
hydroxide
Transcribed Image Text:G. How would you make 350mL of a buffer with a total concentration of 0.75M and a pH of 9.00 from the list of materials below? (your answer should include the volumes of two solutions and the amount of DI water needed to reach the total volume) [remember: vol* total conc->total moles->moles weak, targetpH->ratio->stoich->moles strong] i. A solution of 1.25 M hydrochloric acid ii. A solution of 1.25 M sodium hydroxide iii. A solution of 1.25 M chloroacetic acid (pKa = 2.85) iv. A solution of 1.25 M ammonia (pka = 9.25) v. A solution of 1.25 M carbonic acid (pKa1 = 6.37, pka2 = 10.32 vi. A solution of 1.25 M acetic acid (pka = 4.75) Dilution 1) What would be the volume of weak component and what would be the volume of strong component? Polyprati Chem 129 Topic Set 7 Variations of titration and Buffers Weak MV MV (0.75) (850) = 1.25 (x) pk 2) What would be the capacity of the buffer? behavior x = 210 mL 3) After the buffer is made, what would the pH change to if 24.5mL of 1.25 M hydrochloric acid is added? 4) After the buffer is made, what would pH to IF 37.3 mL of 1.25 M sodium was added change hydroxide
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