chamber Combustion (bomb) calorimeter. In an experiment, a 0.6087 g sample of 2-naphthylacetic acid ( C12H10O2) is burned completely in a bomb calorimeter. The calorimeter is surrounded by 1.201 x 10³ g of water. During the combustion the temperature increases from 23.86 to 26.91 °C. The heat capacity of water is 4.184 J-g¹.C-¹. The heat capacity of the calorimeter was determined in a previous experiment to be 936.5 J. "C-¹, Assuming that no energy is lost to the surroundings, calculate the molar heat of combustion of 2-naphthylacetic acid based on these data. C12H10O2 (s) + (27/2)O2(g) → 5H₂O(l) +12CO₂(g) + Energy Molar Heat of Combustion= kJ/mol

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### Bomb Calorimeter

A bomb calorimeter, also known as a constant volume calorimeter, is a device used to determine the heat of combustion of fuels and the energy content of foods.

#### Diagram Explanation:

- **Outer Structure**: The device consists of an insulated outer chamber containing water.
- **Steel Bomb**: Inside the chamber is a steel container known as the bomb, where the sample is ignited.
- **Sample Dish and Burning Sample**: The sample to be tested is placed inside the dish within the steel bomb.
- **Ignition Wires**: These wires are used to ignite the sample.
- **Thermometer**: Measures the temperature change in the water as the sample burns.
- **Stirrer**: Ensures the even distribution of temperature in the water.

### Experiment Overview:

- **Sample**: A 0.6087 g sample of 2-naphthylacetic acid (C₁₂H₁₀O₂).
- **Calorimeter Content**: Surrounded by 1.201 × 10³ g of water.
- **Temperature Change**: During combustion, the temperature increases from 23.86 to 26.91 °C.
- **Heat Capacity of Water**: 4.184 J·g⁻¹·°C⁻¹.

#### Calculation Details:

- **Calorimeter Capacity**: Determined to be 936.5 J·°C⁻¹ in a prior experiment.
- **Objective**: Calculate the molar heat of combustion for 2-naphthylacetic acid assuming no energy is lost to the surroundings.

#### Reaction:

\[ \text{C}_{12}\text{H}_{10}\text{O}_{2(s)} + \left(\frac{27}{2}\right)\text{O}_{2(g)} \rightarrow 5\text{H}_2\text{O}_{(l)} + 12\text{CO}_2{(g)} + \text{Energy} \]

#### Molar Heat of Combustion:

\[ \text{Molar Heat of Combustion} = \_\_\_\_\_\_ \text{kJ/mol} \]

This setup and experiment help understand the energy release from chemical reactions during combustion.
Transcribed Image Text:### Bomb Calorimeter A bomb calorimeter, also known as a constant volume calorimeter, is a device used to determine the heat of combustion of fuels and the energy content of foods. #### Diagram Explanation: - **Outer Structure**: The device consists of an insulated outer chamber containing water. - **Steel Bomb**: Inside the chamber is a steel container known as the bomb, where the sample is ignited. - **Sample Dish and Burning Sample**: The sample to be tested is placed inside the dish within the steel bomb. - **Ignition Wires**: These wires are used to ignite the sample. - **Thermometer**: Measures the temperature change in the water as the sample burns. - **Stirrer**: Ensures the even distribution of temperature in the water. ### Experiment Overview: - **Sample**: A 0.6087 g sample of 2-naphthylacetic acid (C₁₂H₁₀O₂). - **Calorimeter Content**: Surrounded by 1.201 × 10³ g of water. - **Temperature Change**: During combustion, the temperature increases from 23.86 to 26.91 °C. - **Heat Capacity of Water**: 4.184 J·g⁻¹·°C⁻¹. #### Calculation Details: - **Calorimeter Capacity**: Determined to be 936.5 J·°C⁻¹ in a prior experiment. - **Objective**: Calculate the molar heat of combustion for 2-naphthylacetic acid assuming no energy is lost to the surroundings. #### Reaction: \[ \text{C}_{12}\text{H}_{10}\text{O}_{2(s)} + \left(\frac{27}{2}\right)\text{O}_{2(g)} \rightarrow 5\text{H}_2\text{O}_{(l)} + 12\text{CO}_2{(g)} + \text{Energy} \] #### Molar Heat of Combustion: \[ \text{Molar Heat of Combustion} = \_\_\_\_\_\_ \text{kJ/mol} \] This setup and experiment help understand the energy release from chemical reactions during combustion.
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