CH3 „Ph Ph. „CH3 H-SO4 > (А), HSO4 (B) 9. OH Product (A) & (B) respectively in the above reaction are : (а) Ph - С-NH -CHз, Ph - С-NH - СНз (Ъ) СНз - С-NH-Ph, СH3 - С-NH- Ph (c) Ph - С-NH - СН3, СНз — С-NH - Ph (d) CHз - С-NH-Ph, Ph - С-NH -СHз
CH3 „Ph Ph. „CH3 H-SO4 > (А), HSO4 (B) 9. OH Product (A) & (B) respectively in the above reaction are : (а) Ph - С-NH -CHз, Ph - С-NH - СНз (Ъ) СНз - С-NH-Ph, СH3 - С-NH- Ph (c) Ph - С-NH - СН3, СНз — С-NH - Ph (d) CHз - С-NH-Ph, Ph - С-NH -СHз
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:The question presents a chemical reaction sequence and asks to identify the products labeled as (A) and (B) after reactions with \( \text{H}_2\text{SO}_4 \).
### Reaction Description:
1. **Starting Compound**: The initial compound is an oxime with the structure where a methyl (CH\(_3\)) and phenyl (Ph) groups are attached to the same carbon as the oxime (C=NOH).
2. **Reaction Conditions**:
- **First Reaction**: The compound is treated with sulfuric acid (\( \text{H}_2\text{SO}_4 \)), resulting in Product (A).
- **Second Reaction**: Product (A) undergoes a subsequent reaction with sulfuric acid to form Product (B).
### Options for Product (A) and (B):
- (a) Ph–C–NH–CH\(_3\), Ph–C–NH–CH\(_3\)
- (b) CH\(_3\)–C–NH–Ph, CH\(_3\)–C–NH–Ph
- (c) Ph–C–NH–CH\(_3\), CH\(_3\)–C–NH–Ph
- (d) CH\(_3\)–C–NH–Ph, Ph–C–NH–CH\(_3\)
### Explanation of Structural Representation:
- **Ph** represents a phenyl group (C\(_6\)H\(_5\))
- **C–NH–** signifies a linkage where a carbon is bonded to a nitrogen which is connected to a hydrogen
- In each product, the connections between groups reflect changes from the original oxime structure to amide structures after treatment with \( \text{H}_2\text{SO}_4 \).
The task is to correctly identify products (A) and (B) based on transformation facilitated by sulfuric acid, which typically involves reactions like Beckmann rearrangement in such contexts.
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