Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Related questions
Question
For the following compounds give their absolute configuration at each chiral center

Transcribed Image Text:### Chemical Structures
#### Left Structure:
- **Cyclohexane ring**: A six-membered carbon ring, depicted in a planar hexagonal shape.
- **Bromine (Br) substituent**: Attached to the cyclohexane ring with a wedge bond, indicating it is coming out of the plane towards the observer.
- **Hydroxyl group (OH)**: Also attached to the cyclohexane ring with a wedge bond.
- **Methyl group (CH₃)**: Attached to the same carbon as the hydroxyl group.
#### Right Structure:
- **Cyclohexanone ring**: A six-membered carbon ring with a ketone group (C=O) at the top, forming cyclohexanone.
- **Methyl group (CH₃)**: Attached to the carbon adjacent to the ketone, as shown with a regular bond.
- **Vinyl group (CH₂=CH-)**: Connected to the same carbon as the methyl group, depicted with a wedge bond indicating it is coming out of the plane towards the observer. The double bond between the carbon and CH₂ is shown in a linear fashion.
These structures represent different organic molecules with various functional groups, important for understanding reactivity and stereochemistry in organic chemistry.
Expert Solution

Step 1
Assign priorities to the groups attached to the chiral centre as per CIP rule(Cahn-Ingold-Prelog)
If lowest priority is on dash :-
Clockwise rotation - R configuration
Anticlockwise rotation - S configuration
If lowest priority is on wedge :-
Clockwise rotation - S configuration
Anticlockwise rotation - R configuration
Step by step
Solved in 2 steps with 1 images
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