CH21/23)[Review Topics][References]Draw structures for the carbonyl electrophile and enolate nucleophile that react to give the aldol or enone below.OHCIYou do not have to consider stereochemistry.Draw the enolate ion in its carbanion form.Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner.Separate multiple reactants using the + sign from the drop-down menu.ChemDoodle?<>PreviousNex

Answered: CH21/23) [Review Topics] [References]…

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

See similar textbooks

Similar questions

Follow direction. Do every step.
Draw structures for the carbonyl electrophile and enolate nucleophile that react to give the aldol or enone below. • You do not have to consider stereochemistry. • Draw the enolate ion in its carbanion form. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate multiple reactants using the + sign from the drop-down menu. ChemDoodle Submit Answer Retry Entire Group 7 more group attampts remalning
Please don't provide handwritten solution...
Draw the major product of this elimination. Consider regiochemistry and stereochemistry. Ignore byproducts. (CH3)3CONA, (CH3)3COH heat Drawing Atoms, Bonds and Rings Charges Draw or tap a new bond to see smart suggestions. Undo Reset Remove Done
What is the Aldol addition product formed from the reaction of 3-pentanone with itself? 1. Name the product in the textbox below 2. Draw the product on your file for upload. 3. Add an acid to the above product to dehydrate it. What is the next product? Draw and name it.
Draw the product of this series of reactions. • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • If a group is achiral, do not use wedged or hashed bonds on it. • If the reaction produces a racemic mixture, draw both stereoisomers. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. ● Separate multiple products using the + sign from the drop-down menu. ? 1. Br₂, hv 2. 1 equivalent of NaOEt 3. Br₂ / CH₂Cl₂ ChemDoodle Ⓡ ۵۰ []
Draw the major product of the aldol addition reaction between two equivalents of this ketone with the conditions provided. Ignore inorganic byproducts. 1. NaOH 2. Neutralizing work-up
Write structures for the carbonyl electrophile and enolate nucleophile that react to give the aldol below. ОН You do not have to consider stereochemistry. • Draw the enolate nucleophile in its carbanion form. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate multiple reactants using the + sign from the drop-down menu.
Draw the major product of the aldol addition reaction between two equivalents of this ketone with the conditions provided. Ignore inorganic byproducts. 0 ⑤ 1. NaOH 2. Neutralizing work- up
5. Our base choice determines how much of the original acid is left in solution at equilibrium. This will have significant consequences during our discussion of the Aldol and Claisen reactions. For each of the reactions below determine which is the most acidic proton in the first molecule. Assign a pKa value to at least the most acidic proton. Draw the expected conjugate base and acid. Assign a pKa value to the conjugate acid then determine the approximate position of the equilibrium (towards the starting material, towards the product, or near the middle - for example there would be a significant amount of starting material and product at equilibrium). Then predict the product of the reaction of the conjugate base with the reagent over the next arrow. An example is provided below. Alcohol 16 Lowest pKa =Most acidic Alcohol OH OH 16 OH NaOCH3 Br HO HOCH HO HO HO 16 10 Phenol 38 Amine Albuterol pKa 10 stronger acid pka 16 weaker acid = favored at equilibrium Difference in pKa values = 6…
Help check answers please draw
4. The issue with enol/enolate syntheses is that a lot of the starting materials and products have the same functional groups (carbonyls). To determine which enolate reaction is needed, thus, can depend on more than functional group identification: it sometimes depends on identifying how many carbons are between each carbonyl. So we're going to create a new synthetic map for carbon-carbon bond formations with enols and enolates. Fill in the missing starting materials, reagents, or products as needed, and answer the given questions. a. The aldol, Option 1 ai nip b. The aldol, Option 2 R3 R R3 R² What kind of functional group is this product? · R3 c. The Claisen Condensation R3 OH R¹ R2 Circle the correct answer: The alcohol is (alpha/beta) to the carbonyl. base · + R² OR3 R1 R1 and R2 alkyl, aryl, OR R² Fill in the answer: The product is a (1, ) dicarbonyl

SEE MORE QUESTIONS

Recommended textbooks for you

Chemistry

ISBN:

9781305957404

Author:

Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:

Cengage Learning

Chemistry

ISBN:

9781259911156

Author:

Raymond Chang Dr., Jason Overby Professor

Publisher:

McGraw-Hill Education

Principles of Instrumental Analysis

Chemistry

ISBN:

9781305577213

Author:

Douglas A. Skoog, F. James Holler, Stanley R. Crouch

Publisher:

Cengage Learning

Chemistry

ISBN:

9781305957404

Author:

Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:

Cengage Learning

Chemistry

ISBN:

9781259911156

Author:

Raymond Chang Dr., Jason Overby Professor

Publisher:

McGraw-Hill Education

Principles of Instrumental Analysis

Chemistry

ISBN:

9781305577213

Author:

Douglas A. Skoog, F. James Holler, Stanley R. Crouch

Publisher:

Cengage Learning

Organic Chemistry

Chemistry

ISBN:

9780078021558

Author:

Janice Gorzynski Smith Dr.

Publisher:

McGraw-Hill Education

Chemistry: Principles and Reactions

Chemistry

ISBN:

9781305079373

Author:

William L. Masterton, Cecile N. Hurley

Publisher:

Cengage Learning

Elementary Principles of Chemical Processes, Bind…

Chemistry

ISBN:

9781118431221

Author:

Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard

Publisher:

WILEY

SEE MORE TEXTBOOKS